Highly Efficient and Selective Catalytic N-Alkylation of Amines with Alcohols in Water

被引：29
作者：
Norinder, Jakob [1 ]
Boerner, Armin [1 ,2 ]
机构：
[1] Univ Rostock eV, Leibniz Inst Katalyse, D-18059 Rostock, Germany
[2] Univ Rostock, Inst Chem, D-18059 Rostock, Germany
来源：
CHEMCATCHEM | 2011年 / 3卷 / 09期
关键词：
alcohols; alkylation; amination; iridium; water-soluble catalyst; ASTERISK-IR COMPLEX; REDUCTIVE AMINATION; BORROWING HYDROGEN; TERTIARY-AMINES; IRIDIUM; HYDROAMINATION; CONVERSION; MONOALKYLATION; ANILINES; DIAMINES;
D O I：
10.1002/cctc.201100197
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
引用
收藏
页码：1407 / 1409
页数：3
相关论文
共 71 条
[1]   Ruthenium-complex-catalyzed N-(cyclo)alkylation of aromatic amines with diols.: Selective synthesis of N-(ω-hydroxyalkyl)anilines of type PhNH(CH2)nOH and of some bioactive arylpiperazines [J].
Abbenhuis, RATM ;
Boersma, J ;
van Koten, G .
JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (13) :4282-4290
[2]   Reductive amination of aldehydes and ketones with sodium triacetoxyborohydride. Studies on direct and indirect reductive amination procedures [J].
AbdelMagid, AF ;
Carson, KG ;
Harris, BD ;
Maryanoff, CA ;
Shah, RD .
JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (11) :3849-3862
[3]   Amination of Aliphatic Alcohols and Diols with an Iridium Pincer Catalyst [J].
Andrushko, Natalia ;
Andrushko, Vasyl ;
Roose, Peter ;
Moonen, Kristof ;
Boerner, Armin .
CHEMCATCHEM, 2010, 2 (06) :640-643
[4]   SELECTIVE CONVERSION OF PRIMARY AMINES INTO N,N-DIMETHYLALKYL-AMINE OR N,N-DIALKYLMETHYL-AMINE WITH METHANOL AND RUCL2(PH3P)3 [J].
ARCELLI, A ;
BUITHEKHAI ;
PORZI, G .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 235 (01) :93-96
[5]   Mechanism of homogeneous iridium-catalyzed alkylation of amines with alcohols from a DFT study [J].
Balcells, David ;
Nova, Ainara ;
Clot, Eric ;
Gnanamgari, Dinakar ;
Crabtree, Robert H. ;
Eisenstein, Odile .
ORGANOMETALLICS, 2008, 27 (11) :2529-2535
[6]  
Beauchemin A. M., 2008, ANGEW CHEM, V120, P1432
[7]   Intermolecular cope-type hydroamination of alkenes and alkynes [J].
Beauchemin, Andre M. ;
Moran, Joseph ;
Lebrun, Marie-Eve ;
Seguin, Catherine ;
Dimitrijevic, Elena ;
Zhang, Lili ;
Gorelsky, Serge I. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (08) :1410-1413
[8]   Catalytic Markovnikov and anti-Markovnikov functionalization of alkenes and alkynes: Recent developments and trends [J].
Beller, M ;
Seayad, J ;
Tillack, A ;
Jiao, H .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (26) :3368-3398
[9]  
Beller M, 2004, ANGEW CHEM, V116, P3448
[10]   N-ALKYLATION OF AMINES VIA HOMOGENEOUS CATALYSIS - SYNTHESIS OF CYCLIC MONOAMINES AND DIAMINES [J].
BITSI, G ;
SCHLEIFFER, E ;
ANTONI, F ;
JENNER, G .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 373 (03) :343-352
12345678