Sintering behavior of titanium-titanium nitride nanocomposite powders

被引:26
作者
Dabhade, V. V. [1 ]
Mohan, T. R. Rama [1 ]
Ramakrishnan, P. [1 ]
机构
[1] Indian Inst Technol, Dept Met Engn & Mat Sci, Bombay 400076, Maharashtra, India
关键词
metal matrix composites; nanostructured materials; powder metallurgy; sintering;
D O I
10.1016/j.jallcom.2006.11.187
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The sintering behavior of titanium-titanium nitride nanocomposite powders has been investigated by dilatometry. Micron-sized titanium powders of average particle size of similar to 12 mu m and nano sized titanium nitride powders of average particle size of similar to 50 nm were used to produce two compositions of Ti-8 wt%TiN and Ti-15 wt%TiN by physical mixing and ultrasonification. Dilatometry was carried out by constant rate of heating (10 degrees C/min) to various temperatures in the range of 650-1250 degrees C followed by isothermal holding for I h. The effect of nano TiN dispersion on the sintering onset temperature, linear shrinkage, shrinkage rate, activation energy, and microstructure of titanium was investigated. The sintering of titanium-titanium nitride nanocomposites was found to be influenced by the sintering between the Ti-Ti contacts (self diffusion), Ti-TiN contacts (diffusion of N into Ti), TiN-TiN contacts, the role of oxygen as well as the alpha-beta transformation in titanium. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:215 / 221
页数:7
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