Review of Chitosan-Based Polymers as Proton Exchange Membranes and Roles of Chitosan-Supported Ionic Liquids

被引：103

作者：

Rosli, Nur Adiera Hanna ^{[1
]}

Loh, Kee Shyuan ^{[1
]}

Wong, Wai Yin ^{[1
]}

Yunus, Rozan Mohamad ^{[1
]}

Lee, Tian Khoon ^{[2
]}

Ahmad, Azizan ^{[3
]}

Chong, Seng Tong ^{[4
]}

机构：

[1] Univ Kebangsaan Malaysia, Fuel Cell Inst, Ukm Bangi 43600, Selangor, Malaysia

[2] Uppsala Univ, Dept Chem, Angstrom Lab, SE-75121 Uppsala, Sweden

[3] Univ Kebangsaan Malaysia, Fac Sci & Technol, Ukm Bangi 43600, Selangor, Malaysia

[4] Univ Tenaga Nas, Coll Energy Econ & Social Sci, Jalan IKRAM UNITEN, Kajang 43000, Selangor, Malaysia

来源：

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES | 2020年 / 21卷 / 02期

关键词：

chitosan biopolymer-based membrane; ionic liquids; performance of fuel cell; fuel cell applications; POLY(ETHER ETHER KETONE); SULFONATED GRAPHENE OXIDE; FUEL-CELL MEMBRANES; CONDUCTING COMPOSITE MEMBRANES; METHYLENE PHOSPHONIC CHITOSAN; PHOSPHOTUNGSTIC ACID COMPLEX; LOW METHANOL PERMEABILITY; QUATERNARY AMMONIUM-SALT; COATED CARBON NANOTUBES; ELECTROLYTE MEMBRANE;

D O I：

10.3390/ijms21020632

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Perfluorosulphonic acid-based membranes such as Nafion are widely used in fuel cell applications. However, these membranes have several drawbacks, including high expense, non-eco-friendliness, and low proton conductivity under anhydrous conditions. Biopolymer-based membranes, such as chitosan (CS), cellulose, and carrageenan, are popular. They have been introduced and are being studied as alternative materials for enhancing fuel cell performance, because they are environmentally friendly and economical. Modifications that will enhance the proton conductivity of biopolymer-based membranes have been performed. Ionic liquids, which are good electrolytes, are studied for their potential to improve the ionic conductivity and thermal stability of fuel cell applications. This review summarizes the development and evolution of CS biopolymer-based membranes and ionic liquids in fuel cell applications over the past decade. It also focuses on the improved performances of fuel cell applications using biopolymer-based membranes and ionic liquids as promising clean energy.

引用

页数：52

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