Highly Photostable and Fluorescent Microporous Solids Prepared via Solid-State Entrapment of Boron Dipyrromethene Dyes in a Nascent Metal-Organic Framework

被引：59

作者：

Glembockyte, Viktorija ^{[1
,2
]}

Frenette, Mathieu ^{[1
,2
,3
]}

Mottillo, Cristina ^{[1
,2
]}

Durantini, Andres M. ^{[1
,2
,5
]}

Gostick, Jeff ^{[4
]}

Strukil, Vjekoslav ^{[1
,2
,6
]}

Friscic, Tomislav ^{[1
,2
,6
]}

Cosa, Gonzalo ^{[1
,2
]}

机构：

[1] McGill Univ, Dept Chem, 801 Sherbrooke St W, Montreal, PQ H3A 0B8, Canada

[2] McGill Univ, QCAM, 801 Sherbrooke St W, Montreal, PQ H3A 0B8, Canada

[3] Univ Quebec Montreal, Dept Chim, Case Postale 8888,Succursale Ctr Ville, Montreal, PQ H3C 3P8, Canada

[4] McGill Univ, Dept Chem Engn, 3610 Univ St, Montreal, PQ H3A 0C5, Canada

[5] Univ Nacl Rio Cuarto, Fac Ciencias Exactas Fis Quim & Nat, Dept Quim, Ruta Nacl 36 Km 601,X5804BYA Rio Cuarto, Cordoba, Argentina

[6] Rudjer Boskovic Inst, Bijenicka Cesta 54, Zagreb 10000, Croatia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2018年 / 140卷 / 49期

基金：

加拿大自然科学与工程研究理事会;

关键词：

AGGREGATION-INDUCED EMISSION; ZEOLITIC IMIDAZOLATE FRAMEWORKS; BODIPY DYES; OPTICAL-PROPERTIES; ZIF-8; DERIVATIVES; NANOCOMPOSITES; LUMINESCENCE; ENHANCEMENT; DIFFRACTION;

D O I：

10.1021/jacs.8b09608

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a strategy to synthesize highly emissive, photostable, microporous materials by solid-state entrapment of boron dipyrromethene (BODIPY) fluorophores in a metal organic framework. Solvent-free mechanochemistry or accelerated aging enabled quantitative capture and dispersal of the PM605 dye within the ZIF-8 framework starting from inexpensive, commercial materials. While the design of emissive BODIPY solids is normally challenged by quenching in a densely packed environment, herein reported PM605@ZIF-8 materials show excellent emissive properties and to the best of our knowledge an unprecedented,similar to 10-fold enhancement of BODIPY photostability. Time-resolved and steady-state fluorescence studies of PM605@ZIF-8 show that interchromophore interactions are minimal at low dye loadings, but at higher ones lead to through-pore energy transfer between chromophores and to aggregate species.

引用

页码：16882 / 16887

页数：6

共 72 条

[1] High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].