Study on Direct Synthesis of Energy Efficient Multifunctional Polyaniline-Graphene Oxide Nanocomposite and Its Application in Aqueous Symmetric Supercapacitor Devices

被引:68
作者
Gul, Hajera [1 ]
Shah, Anwar-ul-Haq Ali [2 ]
Krewer, Ulrike [3 ]
Bilal, Salma [1 ,3 ]
机构
[1] Univ Peshawar, Natl Ctr Excellence Phys Chem, Peshawar 25120, Pakistan
[2] Univ Peshawar, Inst Chem Sci, Peshawar 25120, Pakistan
[3] TU Braunschweig, Inst Energy & Proc Syst Engn, D-38106 Braunschweig, Germany
关键词
PANI-GO nanocomposite; aqueous symmetric supercapacitor devices; specific capacitance; IN-SITU GROWTH; HIGH-PERFORMANCE; GRAPHENE/POLYANILINE COMPOSITES; ELECTRODE MATERIAL; OXIDE/POLYANILINE COMPOSITE; ELECTROCHEMICAL PERFORMANCE; CAPACITIVE PERFORMANCE; ASSISTED SYNTHESIS; NANOARRAYS; POLYMERS;
D O I
10.3390/nano10010118
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of promising nanocomposite materials can always be tricky and depends a lot on the method of synthesis itself. Developing such synthesis routes, which are not only simple but also can effectively catch up the synergy of the compositing material, is definitely a worthy contribution towards nanomaterial science. Carbon-based materials, such as graphene oxide, and conjugative polymers, such as conductive polyaniline, are considered materials of the 21st century. This study involves a simple one pot synthesis route for obtaining a nanocomposite of polyaniline and graphene oxide with synergistic effects. The study was carried out in a systematic way by gradually changing the composition of the ingredients in the reaction bath until the formation of nanocomposite took place at some particular reaction parameters. These nanocomposites were then utilized for the fabrication of electrodes for aqueous symmetric supercapacitor devices utilizing gold or copper as current collectors. The device manifested a good capacitance value of 264 F/g at 1 A/g, magnificent rate performance, and capacitance retention of 84.09% at a high current density (10 A/g) when gold sheet electrodes were used as the current collectors. It also showed a capacitance retention of 79.83% and columbic efficiency of 99.83% after 2000 cycles.
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页数:24
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