Combined effect of α-nucleating agents and glass fiber reinforcement on a polypropylene composite: a balanced approach

被引:18
作者
Cui, Linfang [1 ,2 ]
Wang, Penglei [1 ,2 ]
Zhang, Yagang [1 ,2 ,3 ]
Zhang, Letao [1 ,2 ]
Chen, Yurong [1 ,2 ]
Wang, Lulu [1 ,2 ]
Liu, Li [1 ]
Guo, Xinfeng [1 ]
机构
[1] Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Xinjiang Inst Engn, Dept Chem & Environm Engn, Urumqi 830023, Peoples R China
来源
RSC ADVANCES | 2017年 / 7卷 / 68期
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
ISOTACTIC POLYPROPYLENE; MECHANICAL-PROPERTIES; CRYSTALLIZATION KINETICS; FRACTURE-TOUGHNESS; FIBER/POLYPROPYLENE COMPOSITES; BETA-MODIFICATION; MALEIC-ANHYDRIDE; BEHAVIOR; INTERFACE; STRENGTH;
D O I
10.1039/c7ra08322j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein, we demonstrated the mechanical properties and morphologies of modified polypropylene (PP) using a combination of glass fibers (GFs) and alpha-nucleating agents (TMP-6 or TMA-3) at different loadings with the aid of a compatibilizing agent during melt compounding and compression molding. The structural characteristics and properties of modified PP composites were analyzed. The results indicated that TMP-6/GF/PP and TMA-3/GF/PP exhibited significantly enhanced mechanical performance as compared to TMP-6/PP, TMA-3/PP, and neat PP. The influence of the type and concentration of alpha-NAs on the morphology and crystallization behavior of PP composites was also studied. Compared with that of the GF/PP composite, the impact strength of TMA-3/GF/PP increased up to 179.4 J m(-1) at 0.2 wt% of TMA-3 with moderate improvements in tensile strength and flexural modulus. Scanning electron microscopy (SEM) revealed that there was good adhesion at the interface between the GFs and PP matrix. This method provided an alternative approach for the design of novel PP composites.
引用
收藏
页码:42783 / 42791
页数:9
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