Urea derivatives of calix[4]arene 1,3-alternate:: an anion receptor with profound negative allosteric effect

被引：105
|
作者：
Budka, J [1 ]
Lhoták, P [1 ]
Michlová, V [1 ]
Stibor, I [1 ]
机构：
[1] Inst Chem Technol, Dept Organ Chem, Prague 6, Czech Republic
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 08期
关键词：
calixarenes; complexation; NMR titration;
D O I：
10.1016/S0040-4039(00)02309-1
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The complexation behaviour of tetrakis(phenylureido)calix[4]arene in the 1,3-alternate conformation has been studied using NMR titration experiments. It was found that this receptor with two possible binding sites exhibits a strong negative allosteric effect which leads to the exclusive complexation of only one anion. (C) 2001 Elsevier Science Ltd. All rights reserved.
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收藏
页码：1583 / 1586
页数：4
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