N,N′-Bis(2-methylphenyl)-N"-(2,2,2-trichloroacetyl)phosphoric triamide

被引:1
作者
Pourayoubi, Mehrdad [1 ]
Keikha, Mojtaba [1 ]
Parvez, Masood [2 ]
机构
[1] Ferdowsi Univ Mashhad, Dept Chem, Mashhad 91779, Iran
[2] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
PHOSPHORIC TRIAMIDES; CRYSTAL-STRUCTURES; SKELETON;
D O I
10.1107/S1600536811039511
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C16H17Cl3N3O2P, the P-N bonds in the P(O)[NH(2-CH3)C6H4](2) unit [1.623 (4) and 1.637 (3) angstrom] are shorter than the P-N bond in the C(O)NHP(O) fragment [1.704 (3) angstrom]. The phosphoryl and carbonyl groups are anti with respect to each other and the P atom has a distorted tetrahedral configuration. In the crystal, adjacent molecules are linked via N-H center dot center dot center dot O(P) and N-H center dot center dot center dot O(C) hydrogen bonds into an extended chain parallel to [101].
引用
收藏
页码:O2792 / +
页数:10
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