Eco-friendly and techno-economic conversion of CO2 into calcium formate, a valuable resource

被引:9
|
作者
Yoon, Hayoung [1 ]
Yoon, Taeksang [2 ]
Yoon, Ha-Jun [2 ]
Lee, Chul-Jin [2 ,3 ]
Yoon, Sungho [1 ]
机构
[1] Chung Ang Univ, Dept Chem, 84 Heukseok Ro, Seoul, South Korea
[2] Chung Ang Univ, Sch Chem Engn & Mat Sci, 84 Heukseok Ro, Seoul, South Korea
[3] Chung Ang Univ, Dept Intelligent Energy & Ind, 84 Heukseok Ro, Seoul, South Korea
基金
新加坡国家研究基金会;
关键词
CARBON-DIOXIDE; FORMIC-ACID; METHANOL PRODUCTION; TRIETHYLAMINE; TECHNOLOGIES; EFFICIENCY; FEEDSTOCK; CATALYSIS; CAPTURE; ENERGY;
D O I
10.1039/d1gc04606c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The suppression of greenhouse gas emissions is being considered more important than ever, and consequently, the development of methods to produce useful CO2 conversion products with excellent techno-economic feasibility and high CO2 reduction capability is of interest. A continuous CO2 conversion system and a heterogenized hydrogenation catalyst can be used to develop a process for the efficient and selective production of Ca(HCO2)(2), which has not been considered as a CO2 conversion product so far, from waste resources, including CaO. Techno-economic analysis of the entire process showed that the production cost of Ca(HCO2)(2) was reduced by around 16% compared with the conventional process, indicating a high possibility of market penetration. Furthermore, the estimation of the global warming index of the process through a life-cycle assessment showed that the global warming index could be reduced by about 20% compared with that of existing Ca(HCO2)(2) production processes.
引用
收藏
页码:1738 / 1745
页数:8
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