catena-poly[[bis(1H-benzimidazole-κN3)(salicylato-κO)copper(II)]-μ-salicylato-O,O′:O"]

被引：82
作者：
Li, H
Yin, KL
Xu, DJ [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[2] Jiangsu Polytech Univ, Key Lab Fine Chem Engn, Zhengzhou, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷
关键词：
D O I：
10.1107/S0108270104029580
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Cu(C7H5O3)(2)(C7H6N2)(2)](n), is a one-dimensional polymeric complex bridged by salicylate anions. The Cu-II atom is surrounded by three salicylate and two benzimidazole ligands, with a tetragonally elongated octahedral coordination geometry. The Cu - O bond distances in the axial directions are 2.6092 ( 16) and 2.6834 ( 17) Angstrom. pi-pi stacking interactions exist between the benzimidazole rings of neighboring polymeric complex chains.
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页码：M19 / M21
页数：3
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