Rhodium-Catalyzed Asymmetric Arylation of Azomethine Imines

被引：43
|
作者：
Shintani, Ryo [1 ]
Soh, Ying-Teck [1 ]
Hayashi, Tamio [1 ]
机构：
[1] Kyoto Univ, Dept Chem, Grad Sch Sci, Sakyo Ku, Kyoto 6068502, Japan
来源：
ORGANIC LETTERS | 2010年 / 12卷 / 18期
关键词：
CHIRAL DIENE LIGANDS; ENANTIOSELECTIVE 1,3-DIPOLAR CYCLOADDITION; STEERING LIGANDS; CONJUGATE ADDITIONS; ARYLBORONIC ACIDS; ALLYLIC ALCOHOLS; LEWIS-ACIDS; C-C; 1,4-ADDITION; COMPLEXES;
D O I：
10.1021/ol101700v
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A rhodium-catalyzed addition of sodium tetraarylborates to azomethine imines has been described. Highly efficient asymmetric catalysis has also been achieved by employing a chiral diene ligand to give 1-(diarylmethyl)pyrazolidin-3-ones with high enantioselectivity.
引用
收藏
页码：4106 / 4109
页数：4
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