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One-pot synthesis of amphiphilic polymeric Janus particles and their self-assembly into supermicelles with a narrow size distribution
被引:147
|作者:
Nie, Lei
[1
]
Liu, Shiyong
[1
]
Shen, Wenming
[1
]
Chen, Daoyong
[1
]
Jiang, Ming
[1
]
机构:
[1] Univ Sci & Technol China, Dept Polymer Sci & Engn, Hefei 230026, Anhui, Peoples R China
关键词:
Janus particles;
micelles;
nanostructures;
self-assembly;
supramolecular chemistry;
NANOPARTICLES;
MICELLES;
SURFACES;
MICROSPHERES;
DESIGN;
D O I:
10.1002/anie.200700209
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
(Figure Presented) Not just a pretty structure: Water-dispersible hybrid nanotubes were used as a desymmetrization tool to prepare Janus nanoparticles consisting of a hydrophobic sphere with water-soluble polymer chains grafted on one side (see picture). The Janus micelles undergo self-assembly to form supermicelles with a flowerlike morphology in which the constituent Janus particles are the "petals". © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码:6321 / 6324
页数:4
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