Dinuclear complexes of europium(III) and gadolinium(III) ions with a julolidine-quinoline-based tridentate ligand

被引：4

作者：

Fanna, Daniel J. ^{[1
]}

Zhang, Yingjie ^{[2
]}

Salih, Anya ^{[3
]}

Reynolds, Jason K. ^{[1
]}

Li, Feng ^{[1
]}

机构：

[1] Univ Western Sydney, Sch Sci & Hlth, Penrith, NSW, Australia

[2] Australian Nucl Sci & Technol Org, Kirrawee, Australia

[3] Univ Western Sydney, Confocal Bioimaging Facil, Res & Dev Div, Hawkesbury Campus, Penrith, NSW, Australia

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2016年 / 69卷 / 11-13期

关键词：

Dinuclear; europium(III); gadolinium(III); julolidine; quinoline; COLORIMETRIC CHEMOSENSOR; LANTHANIDE COMPLEXES; FLUORESCENT SENSOR; AQUEOUS-MEDIA; LUMINESCENT; CRYSTALLOGRAPHY; DERIVATIVES; CYANIDE; FE(II); AL3+;

D O I：

10.1080/00958972.2016.1194403

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of europium(III) or gadolinium(III) acetates with a Schiff base ligand {HL (C22H21N3O)=((E)-9-((quinolin-8-ylimino)methyl)-1,2,3,5,6,7-hexahydropyrido[3,2,1-ij]quinolin-8-ol)} in methanol affords two dinuclear complexes which have been characterized by powder X-ray diffraction, Raman spectroscopy, scanning electron microscope-electron dispersive spectroscopy, absorption and emission spectroscopies as well as single-crystal X-ray diffraction. [Eu2L2(CH3COO)(4)(CH3OH)(2)] (1) and [Gd2L2(CH3COO)(4)(CH3OH)(2)] (2) are iso-structures, each consisting of two M:L:CH3COO:CH3OH (1:1:1:1) units bridged by two acetate anions with the metal center in a distorted capped square antiprismatic coordination geometry. Their vibration modes, electronic structures, and photoluminescent properties are reported. [GRAPHICS] .

引用

页码：1883 / 1892

页数：10

共 50 条

[41] Cationic dinuclear Ir(III) complexes based on acylhydrazine ligands: Reversible piezochromic luminescence and AIE behaviours [J].

Xie, Jiaxin ;

Li, Dan ;

Duan, Yingchen ;

Geng, Yun ;

Yang, Tianzhi ;

Li, Guangfu ;

Zhu, Dongxia ;

Su, Zhongmin .

DYES AND PIGMENTS, 2020, 172

[42] Enhanced Optoelectronics Features of Eu(III) Complexes Based on Microwave Assisted Ligand and Nitrogen Containing Ancillary Ligands [J].

Kumar, Satish ;

Bala, Manju ;

Taxak, V. B. ;

Devi, Rekha ;

Khatkar, S. P. .

JOURNAL OF NANOELECTRONICS AND OPTOELECTRONICS, 2015, 10 (01) :41-45

[43] Ligand-Field Asymmetry-Controlled Luminescent Europium (III) and Samarium(III) Tris(β-diketonate) Complexes of Diphenyl-(2-pyridyl-N-oxide)- Phosphine Oxide [J].

Vats, Bal Govind ;

Kannan, Shanmugaperumal ;

Kumar, Mukesh ;

Drew, Micheal G. B. .

CHEMISTRYSELECT, 2017, 2 (13) :3683-3689

[44] Structural and NMR Characterization of Sm(III), Eu(III), and Yb(III) Complexes of an Amide Based Polydentate Ligand Exhibiting Paramagnetic Chemical Exchange Saturation Transfer Abilities [J].

Dorweiler, Jason D. ;

Nemykin, Victor N. ;

Ley, Amanda N. ;

Pike, Robert D. ;

Berry, Steven M. .

INORGANIC CHEMISTRY, 2009, 48 (19) :9365-9376

[45] Synthesis and characterization of green-emitting Ir(III) complexes based on a functionalized benzimidazole ligand [J].

Yu, Tianzhi ;

Yang, Fuzhi ;

Chen, Xiaolian ;

Su, Wenming ;

Zhao, Yuling ;

Zhang, Hui ;

Li, Jianfeng .

NEW JOURNAL OF CHEMISTRY, 2017, 41 (05) :2046-2054

[46] Effect of auxiliary-ligand on assembly of lanthanide(III) complexes with quinoline-2-carboxylic acid: Synthesis, structure, photoluminescent and magnetic properties [J].

Ye, Junwei ;

Wang, Qianqian ;

Gao, Hongze ;

Lu, Xinyi ;

Gong, Weitao ;

Lin, Yuan ;

Ning, Guiling .

INORGANICA CHIMICA ACTA, 2012, 384 :1-7

[47] Designing of europium(III) complexes with β-keto carboxylic acid and nitrogen-containing secondary ligand possessing optoelectrical, Urbach energy and lasing properties [J].

Kumari, Poonam ;

Khatri, Savita ;

Ahlawat, Pratibha ;

Hooda, Pooja ;

Taxak, V. B. ;

Khatkar, S. P. ;

Kumar, Rajesh .

JOURNAL OF CHEMICAL SCIENCES, 2022, 135 (01)

[48] Two zinc(II) coordination complexes based on an asymmetric multidentate ligand: syntheses, structures, selective fluorescence sensing of iron(III) ions and thermal analyses [J].

Liu, Yaru ;

Liu, Lan ;

Zhang, Xiao ;

Liang, Guorui ;

Gong, Xuebing .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2018, 74 :13-+

[49] Morphology and Luminescent Properties of Solid Micelles based on Europium(III) Complexes with Diblock Copolymers of Methyl Methylacrylate and Acrylic Acid [J].

Wang, Die ;

Tang, Jianguo ;

Wang, Xinzhi ;

Shen, Wenfei ;

Wang, Yao ;

Wang, Yanxin ;

Liu, Jixian ;

Huang, Linjun ;

Jiao, Jiqing ;

Song, Yan ;

Belfiore, Laurence A. .

FERROELECTRICS, 2015, 486 (01) :91-105

[50] New dinuclear Schiff base complexes of iron(II/III) and copper(II) ions: synthesis, crystal structure, and DNA-binding studies [J].

U-Wang, O. ;

Singh, Rajkumar Bhubon ;

Devi, Wahengbam Bembee ;

Singh, Usham Ibotomba ;

Devi, Rajkumari Bindiya ;

Devi, Oinam Bijeta ;

Shahani, Ramina ;

Swu, Toka .

INORGANIC AND NANO-METAL CHEMISTRY, 2019, 49 (11) :363-374

← 1 2 3 4 5 →