Threading the needle: guest transport in a versatile 0D porous molecular crystal

被引：15
作者：
Nikolayenko, Varvara I. [1 ]
Heyns, Anneli [1 ]
Barbour, Leonard J. [1 ]
机构：
[1] Univ Stellenbosch, Dept Chem & Polymer Sci, ZA-7600 Matieland, South Africa
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 82期
基金：
新加坡国家研究基金会;
关键词：
METAL-ORGANIC-FRAMEWORKS; SINGLE-CRYSTAL; COORDINATION POLYMER; GAS-ADSORPTION; TRANSFORMATIONS; HYDROGEN; REMOVAL; SEPARATION; EXCHANGE; SORPTION;
D O I：
10.1039/c7cc06676g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Porous host crystals of the metallocycle [Cu-2(1,3-bis(imidazol-1-ylmethyl)- 2,4,6-trimethylbenzene)(2)Cl-4] center dot 2CH(3)OH are permeable to a series of small organic guests despite their lack of permanent channels. It is inferred from single crystal X-ray diffraction that transport of the guest molecules is facilitated by "flapping'' of the imidazolyl rings.
引用
收藏
页码：11306 / 11309
页数：4
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