Threading the needle: guest transport in a versatile 0D porous molecular crystal

被引：16

作者：

Nikolayenko, Varvara I. ^{[1
]}

Heyns, Anneli ^{[1
]}

Barbour, Leonard J. ^{[1
]}

机构：

[1] Univ Stellenbosch, Dept Chem & Polymer Sci, ZA-7600 Matieland, South Africa

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 82期

基金：

新加坡国家研究基金会;

关键词：

METAL-ORGANIC-FRAMEWORKS; SINGLE-CRYSTAL; COORDINATION POLYMER; GAS-ADSORPTION; TRANSFORMATIONS; HYDROGEN; REMOVAL; SEPARATION; EXCHANGE; SORPTION;

D O I：

10.1039/c7cc06676g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Porous host crystals of the metallocycle [Cu-2(1,3-bis(imidazol-1-ylmethyl)- 2,4,6-trimethylbenzene)(2)Cl-4] center dot 2CH(3)OH are permeable to a series of small organic guests despite their lack of permanent channels. It is inferred from single crystal X-ray diffraction that transport of the guest molecules is facilitated by "flapping'' of the imidazolyl rings.

引用

页码：11306 / 11309

页数：4

共 55 条

[1] Building co-crystals with molecular sense and supramolecular sensibility [J].

Aakeröy, CB ;

Salmon, DJ .

CRYSTENGCOMM, 2005, 7 :439-448

[2] A Review on Breathing Behaviors of Metal-Organic-Frameworks (MOFs) for Gas Adsorption [J].

Alhamami, Mays ;

Doan, Huu ;

Cheng, Chil-Hung .

MATERIALS, 2014, 7 (04) :3198-3250

[3] A new type of material for the recovery of hydrogen from gas mixtures [J].

Atwood, JL ;

Barbour, LJ ;

Jerga, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (22) :2948-2950

[4] Guest transport in a nonporous organic solid via dynamic van der Waals cooperativity [J].

Atwood, JL ;

Barbour, LJ ;

Jerga, A ;

Schottel, BL .

SCIENCE, 2002, 298 (5595) :1000-1002

[5] A crystalline organic substrate absorbs methane under STP conditions [J].

Atwood, JL ;

Barbour, LJ ;

Thallapally, PK ;

Wirsig, TB .

CHEMICAL COMMUNICATIONS, 2005, (01) :51-53

[6]

Barbour L. J., 2012, SUPRAMOLECULAR CHEM

[7]

Barbour L.J., 2001, J SUPRAMOL CHEM, V1, P189, DOI [DOI 10.1016/S1472-7862(02)00030-8, 10.1016/S1472-7862(02)00030-8]

[8] Crystal porosity and the burden of proof [J].

Barbour, LJ .

CHEMICAL COMMUNICATIONS, 2006, (11) :1163-1168

[9] Toxic gas removal - metal-organic frameworks for the capture and degradation of toxic gases and vapours [J].

Barea, Elisa ;

Montoro, Carmen ;

Navarro, Jorge A. R. .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :5419-5430

[10] Hierarchy of supramolecular synthons:: Persistent hydroxyl•••pyridine hydrogen bonds in cocrystals that contain a cyano acceptor [J].

Bis, Joanna A. ;

Vishweshwar, Peddy ;

Weyna, David ;

Zaworotko, Michael J. .

MOLECULAR PHARMACEUTICS, 2007, 4 (03) :401-416

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