Co-pyrolysis of South African bituminous coal and Scenedesmus microalgae: Kinetics and synergistic effects study

In this work, the co-pyrolysis of coal and algae is explored with special emphasis on decomposition kinetics and the possibility of the existence of synergistic effects. Modelling and kinetics analysis based approaches were used for the investigation of the existence of synergistic effects. The co-pyrolysis kinetics was studied using the model-free, Coats-Redfern integral method. The kinetics were evaluated for 1st and 2nd order reaction models. Results reveal that Scenedesmus microalgae is characterised by a two stage decomposition process that occurs at temperature ranges of 200-400 degrees C and 500-700 degrees C with activation energy of 145.5 and 127.3 kJ/mol, respectively. Bituminous coal has a two stage, slow decomposition process that occurs at temperature ranges of 400-700 degrees C and above 750 degrees C with an activation energy of 81.8 and 649.3 kJ/mol, respectively. Furthermore, co-pyrolysis of coal and microalgae is characterised by three stages whose kinetics are dominated by the pyrolysis of the individual materials. For the studied range of coal/algae ratios, the three pyrolysis stages occur in the approximate temperature ranges of 200-400 degrees C, 430-650 degrees C and above 750 degrees C, with activation energies in the ranges of 131-138, 72-78 and 864.5-1235 kJ/mol, respectively. Modelling and kinetics study showed that there is strong evidence of interactions between coal and microalgae that manifest as synergistic effects especially in the second and third stages of decomposition.