Polysaccharides of saponin-bearing plants.: XIV.: Structural study of glucoarabinogalactan from Acanthophyllum pungens roots

被引:2
作者
Arifkhodzhaev, AO [1 ]
Kurbanova, AD
Rakhimov, DA
Shashkov, AS
机构
[1] Acad Sci Republ Uzbekistan, S Yu Yunusov Inst Chem Plant Subst, Tashkent, Uzbekistan
[2] Russian Acad Sci, ND Zelinskii Inst Organ Chem, Moscow, Russia
关键词
Acanthophyllum pungens; polysaccharide; glucoarabinogalactan; oligosaccharides; galactobiose; galactotriose; galactotetraose; structure;
D O I
10.1023/A:1024849527417
中图分类号
R914 [药物化学];
学科分类号
100701 ;
摘要
The structure of the polysaccharide glucoarabinogalactan, which is a branched polysaccharide, was established by chemical and spectral methods. Its main chain consists of alpha-1-->6-bound galactopyranose units. Galactopyranose atoms C-2 and C-3 act as branching points. The side chains contain galactopyranose, glucopyranose, and chains of beta-(1-->3)-bound arabinopyranose units. The linear structures of three galactooligosaccharides were identified and proved by partial acid hydrolysis.
引用
收藏
页码:154 / 157
页数:4
相关论文
共 10 条
[1]  
ARIFKHODZHAEV AO, 1993, KHIM PRIR SOEDIN+, P188
[2]  
Arifkhodzhaev AO, 1994, KHIM PRIR SOEDIN+, P709
[3]  
Arifkhodzhaev AO, 1997, KHIM PRIR SOEDIN+, P693
[4]  
BOSE S, 1973, INDIAN J CHEM, V11, P996
[5]   FURTHER STUDIES ON ASSIGNMENT OF SIGNALS IN C-13 MAGNETIC-RESONANCE SPECTRA OF ALDOSES AND DERIVED METHYL GLYCOSIDES [J].
GORIN, PAJ ;
MAZUREK, M .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1975, 53 (08) :1212-1223
[6]  
HAKOMORI SI, 1964, J BIOCHEM-TOKYO, V55, P205
[7]  
KARACSONYI S, 1984, CARBOHYD RES, V134, P265, DOI 10.1016/0008-6215(84)85042-9
[8]  
KOCHETKOV, 1967, CARBOHYDRATE CHEM ME, P259
[9]  
LANCE DJ, 1995, CAN J CHEM, V45, P1967
[10]  
SHASHKOV AS, 1976, BIOORG KHIM+, V2, P437