Oxygen reduction using a metal-free naphthalene diimide-based covalent organic framework electrocatalyst

被引:60
作者
Royuela, Sergio [1 ]
Martinez-Perinan, Emiliano [3 ]
Arrieta, Marina P. [1 ]
Martinez, Jose, I [4 ]
Mar Ramos, M. [2 ]
Zamora, Felix [5 ,6 ,7 ,8 ]
Lorenzo, Encarnacion [3 ,6 ,7 ]
Segura, Jose L. [1 ]
机构
[1] Univ Complutense Madrid, Dept Quim Organ 1, Fac CC Quim, E-28040 Madrid, Spain
[2] Univ Rey Juan Carlos, Dept Tecnol Quim & Ambiental, Madrid 28933, Spain
[3] Univ Autonoma Madrid, Dept Quim Analit & Anal Instrumental, Fac Ciencias, E-28049 Madrid, Spain
[4] CSIC, ICMM, Dept Nanoestruct Superficies Recubrimientos & Ast, Madrid 28049, Spain
[5] Univ Autonoma Madrid, Dept Quim Inorgan, Fac Ciencias, E-28049 Madrid, Spain
[6] Inst Madrileno Estudios Avanzados Nanociencia IMD, Madrid 28049, Spain
[7] Univ Autonoma Madrid, Inst Adv Res Chem Sci IAdChem, E-28049 Madrid, Spain
[8] Univ Autonoma Madrid, Condensed Matter Phys Ctr IFIMAC, E-28049 Madrid, Spain
关键词
DELAMINATION;
D O I
10.1039/c9cc06479f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel naphthalene diimide-based covalent organic framework (NDI-COF) has been synthesized and successfully exfoliated into COF nanosheets (CONs). Electrochemical measurements reveal that the naphthalene diimide units incorporated into NDI-CONs act as efficient electrocatalyst for oxygen reduction in alkaline media, showing its potential for the development of metal-free fuel cells.
引用
收藏
页码:1267 / 1270
页数:4
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