Recent advances in metalloporphyrins for environmental and energy applications

被引：57

作者：

Zhang, Peng ^{[1
,2
]}

Hu, Jingping ^{[1
,2
]}

Liu, Bingchuan ^{[1
,2
]}

Yang, Jiakuan ^{[1
,2
]}

Hou, Huijie ^{[1
,2
]}

机构：

[1] Huazhong Univ Sci & Technol, Sch Environm Sci & Engn, Wuhan 430074, Hubei, Peoples R China

[2] Huazhong Univ Sci & Technol, Hubei Prov Engn Lab Solid Waste Treatment Disposa, Wuhan 430074, Hubei, Peoples R China

来源：

CHEMOSPHERE | 2019年 / 219卷

基金：

中国国家自然科学基金;

关键词：

Porphyrin; Fenton-like oxidation; High-valent iron species; Photocatalysis; IRON-PORPHYRIN COMPLEXES; METAL-ORGANIC FRAMEWORK; O BOND-CLEAVAGE; ELECTROCATALYTIC O-2 REDUCTION; PHOTOINDUCED ELECTRON-TRANSFER; BIOMIMETIC CATALYTIC-SYSTEM; MG CHLOROPHYLL-A; RESONANCE RAMAN; WATER OXIDATION; HYDROGEN-PEROXIDE;

D O I：

10.1016/j.chemosphere.2018.12.024

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Porphyrin-based chemistry has reached an unprecedented period of rapid development after decades of study. Due to attractive multifunctional properties, porphyrins and their analogues have emerged as multifunctional organometals for environmental and energy purposes. In particular, pioneer works have been conducted to explore their application in pollution abatement, energy conversion and storage and molecule recognition. This review summarizes recent advances of porphyrins chemistry, focusing on elucidating the nature of catalytic process. The Fenton-like redox chemistry and photo-excitability of porphyrins and their analogues are discussed, highlighting the generation of high-valent iron oxo porphyrin species. Finally, challenges in current research are identified and perspectives for future development in this area are presented. (C) 2018 Elsevier Ltd. All rights reserved.

引用

页码：617 / 635

页数：19