Conceptual integration of homogeneous and heterogeneous catalyses

被引：22

作者：

Tada, Mizuki ^{[1
]}

Motokura, Ken ^{[1
]}

Iwasawa, Yasuhiro ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

TOPICS IN CATALYSIS | 2008年 / 48卷 / 1-4期

关键词：

design of catalyst surfaces; bifunctional catalysis; active structures; supported metal complexes; immobilization; surface functionalization; in situ characterization; time-resolved XAFS; C-C coupling; asymmetric Diels-Alder reaction; alkene hydroformylation; acid-base catalyst; Cu-BOX complex; Rh dimers;

D O I：

10.1007/s11244-008-9049-4

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This article illustrates how bifunctional catalyst surfaces are created by modifying oxide surfaces with organic functional groups and/or with metal complexes, summarizing our previous reports and also presenting new data. which provide a new class of catalytic materials with a high complexity for selective catalysis including C-C coupling, hydroformylation, and asymmetric reactions. The catalyst surfaces are characterized by in situ physical analysis techniques such as time-resolved XAFS, FT-IR, solid-state MAS NMR and so on.

引用

页码：32 / 40

页数：9

共 57 条

[1] Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure [J].

Ankudinov, AL ;

Ravel, B ;

Rehr, JJ ;

Conradson, SD .

PHYSICAL REVIEW B, 1998, 58 (12) :7565-7576

[2] METAL-ASSISTED HYDROFORMYLATION ON A SIO2-ATTACHED RH DIMER - INSITU EXAFS AND FT-IR OBSERVATIONS OF THE DYNAMIC BEHAVIORS OF THE DIMER SITE [J].

ASAKURA, K ;

KITAMURABANDO, K ;

IWASAWA, Y ;

ARAKAWA, H ;

ISOBE, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (25) :9096-9104

[3]

Bae SJ, 2000, CHEM COMMUN, P31

[4] Surface structures and catalytic hydroformylation activities of Rh dimers attached on various inorganic oxide supports [J].

Bando, KK ;

Asakura, K ;

Arakawa, H ;

Isobe, K ;

Iwasawa, Y .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (32) :13636-13645

[5] Modified BINOL ligands in asymmetric catalysis [J].

Chen, Y ;

Yekta, S ;

Yudin, AK .

CHEMICAL REVIEWS, 2003, 103 (08) :3155-3211

[6] ORGANIC-SYNTHESIS INVOLVING MULTI-POLYMER REACTIONS - POLYMERIC TRITYLLITHIUM [J].

COHEN, BJ ;

KRAUS, MA ;

PATCHORNIK, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (12) :4165-4167

[7] Chiral copper(II) bisoxazoline covalently anchored to silica and mesoporous MCM-41 as a heterogeneous catalyst for the enantioselective Friedel-Crafts hydroxyalkylation [J].

Corma, A ;

García, H ;

Moussaif, A ;

Sabater, MJ ;

Zniber, R ;

Redouane, A .

CHEMICAL COMMUNICATIONS, 2002, (10) :1058-1059

[8] TOTAL SYNTHESIS OF (+)-A83543A [(+)-LEPICIDIN-A] [J].

EVANS, DA ;

BLACK, WC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (11) :4497-4513

[9] Bis(oxazoline) and bis(oxazolinyl)pyridine copper complexes as enantioselective Diels-Alder catalysts: Reaction scope and synthetic applications [J].

Evans, DA ;

Barnes, DM ;

Johnson, JS ;

Lectka, R ;

von Matt, P ;

Miller, SJ ;

Murry, JA ;

Norcross, RD ;

Shaughnessy, EA ;

Campos, KR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (33) :7582-7594

[10] In situ, time resolved, and simultaneous multi-edge determination of local order change during reduction of supported bimetallic (Pt-Ge) catalyst precursors using energy dispersive EXAFS [J].

Fiddy, SG ;

Newton, MA ;

Campbell, T ;

Corker, JM ;

Dent, AJ ;

Harvey, I ;

Salvini, G ;

Turin, S ;

Evans, J .

CHEMICAL COMMUNICATIONS, 2001, (05) :445-446

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