Energy transfer, tunable photoluminescence of Sr 3 Lu(PO 4 ) 3:Tb 3+, Eu 3+phosphors

被引:16
作者
Xie, Mubiao [1 ]
Ruan, Wenke [1 ]
Wang, Jing [1 ]
机构
[1] Lingnan Normal Univ, Sch Chem & Chem Engn, Key Lab Clean Energy Mat Chem Guangdong Higher Ed, Zhanjiang 524048, Peoples R China
基金
中国国家自然科学基金;
关键词
LUMINESCENCE; PHOSPHORS; SENSITIZER; EMISSION; TERBIUM; CE3+; TB3+;
D O I
10.1016/j.jlumin.2020.117278
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Series of Tb3+ or Eu3+ singly doped and Tb3+/Eu3+ co-doped Sr3Lu(PO4)3 phosphors were prepared by the high temperature solid reaction method. Compared with the excitation spectra of Tb3+ singly doped samples, the effective excitation range of Tb3+/Eu3+ co-doped samples is extended in the near UV region, and the excitation intensity in range 330–380 nm is enhanced. The existence of energy transfer from Tb3+ to Eu3+ ions was confirmed by photoluminescence spectra and lifetime measurements. Under the excitation of 377 nm, the characteristic emission peaks of Tb3+ and Eu3+ ions were both observed, and the ratio of green and red emission components was changed by increasing the concentration of Eu3+. Hence, the emission color of samples Sr3Lu1-x(PO4)3:0.08Tb3+, xEu3+ (x = 0, 0.02, 0.04, 0.06, 0.08 and 0.10) can be turned from green to red region. © 2020 Elsevier B.V.
引用
收藏
页数:5
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