Energy transfer, tunable photoluminescence of Sr 3 Lu(PO 4 ) 3:Tb 3+, Eu 3+phosphors

被引:12
作者
Xie, Mubiao [1 ]
Ruan, Wenke [1 ]
Wang, Jing [1 ]
机构
[1] Lingnan Normal Univ, Sch Chem & Chem Engn, Key Lab Clean Energy Mat Chem Guangdong Higher Ed, Zhanjiang 524048, Peoples R China
基金
中国国家自然科学基金;
关键词
LUMINESCENCE; PHOSPHORS; SENSITIZER; EMISSION; TERBIUM; CE3+; TB3+;
D O I
10.1016/j.jlumin.2020.117278
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Series of Tb3+ or Eu3+ singly doped and Tb3+/Eu3+ co-doped Sr3Lu(PO4)3 phosphors were prepared by the high temperature solid reaction method. Compared with the excitation spectra of Tb3+ singly doped samples, the effective excitation range of Tb3+/Eu3+ co-doped samples is extended in the near UV region, and the excitation intensity in range 330–380 nm is enhanced. The existence of energy transfer from Tb3+ to Eu3+ ions was confirmed by photoluminescence spectra and lifetime measurements. Under the excitation of 377 nm, the characteristic emission peaks of Tb3+ and Eu3+ ions were both observed, and the ratio of green and red emission components was changed by increasing the concentration of Eu3+. Hence, the emission color of samples Sr3Lu1-x(PO4)3:0.08Tb3+, xEu3+ (x = 0, 0.02, 0.04, 0.06, 0.08 and 0.10) can be turned from green to red region. © 2020 Elsevier B.V.
引用
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页数:5
相关论文
共 24 条
  • [1] [Anonymous], 1970, J. Solid State Chem, DOI DOI 10.1016/0022-4596(70)90028-9
  • [2] [Anonymous], [No title captured]
  • [3] STRUCTURAL REFINEMENTS OF EULYTITE-TYPE CA3BI(PO4)3 AND BA3LA(PO4)3
    BARBIER, J
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1992, 101 (02) : 249 - 256
  • [4] Mechanistic Insight into Energy-Transfer Dynamics and Color Tunability of Na4CaSi3O9:Tb3+,Eu3+ for Warm White LEDs
    He, Jin
    Yan, Cheng
    Huang, Minmin
    Shi, Rui
    Chen, Yibo
    Ling, Chris D.
    Liu, Zhao-Qing
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2020, 26 (25) : 5619 - 5628
  • [5] Enhancing solar cell efficiency: the search for luminescent materials as spectral converters
    Huang, Xiaoyong
    Han, Sanyang
    Huang, Wei
    Liu, Xiaogang
    [J]. CHEMICAL SOCIETY REVIEWS, 2013, 42 (01) : 173 - 201
  • [6] Synthesis, structure and photoluminescence properties of europium-, terbium-, and thulium-doped Ca3Bi(PO4)3 phosphors
    Jiao, Mengmeng
    Guo, Ning
    Lu, Wei
    Jia, Yongchao
    Lv, Wenzhen
    Zhao, Qi
    Shao, Baiqi
    You, Hongpeng
    [J]. DALTON TRANSACTIONS, 2013, 42 (34) : 12395 - 12402
  • [7] Energy transfer and tunable photoluminescence of LaBWO6:Tb3+,Eu3+ phosphors for near-UV white LEDs
    Li, Bin
    Huang, Xiaoyong
    Guo, Heng
    Zeng, Yujia
    [J]. DYES AND PIGMENTS, 2018, 150 : 67 - 72
  • [8] Recent progress in luminescence tuning of Ce3+ and Eu2+-activated phosphors for pc-WLEDs
    Li, Guogang
    Tian, Ying
    Zhao, Yun
    Lin, Jun
    [J]. CHEMICAL SOCIETY REVIEWS, 2015, 44 (23) : 8688 - 8713
  • [9] Structure, luminescence properties and energy transfer of Tb3+-Eu3+ codoped LiBaB9O15 phosphors
    Li, Ting
    Li, Panlai
    Wang, Zhijun
    Xu, Shuchao
    Bai, Qiongyu
    Yang, Zhiping
    [J]. DALTON TRANSACTIONS, 2015, 44 (38) : 16840 - 16846
  • [10] CaGdAlO4:Tb3+/Eu3+ as promising phosphors for full-color field emission displays
    Li, Xuejiao
    Zhang, Yang
    Geng, Dongling
    Lian, Jianshe
    Zhang, Guo
    Hou, Zhiyao
    Lin, Jun
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2014, 2 (46) : 9924 - 9933