High-Spin Square-Planar CoII and FeII Complexes and Reasons for Their Electronic Structure

被引：69
作者：
Cantalupo, Stefanie A. [1 ]
Fiedler, Stephanie R. [2 ]
Shores, Matthew P. [2 ]
Rheingold, Arnold L. [3 ]
Doerrer, Linda H. [1 ]
机构：
[1] Boston Univ, Dept Chem, Boston, MA 02215 USA
[2] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA
[3] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 04期
基金：
美国国家科学基金会;
关键词：
cobalt; electronic structure; high-spin complexes; iron; square-planar complexes; TRANSITION-METAL-COMPLEXES; CR QUADRUPLE BOND; CRYSTAL-STRUCTURES; COBALT(II) COMPLEXES; MAGNETIC-PROPERTIES; MESO-OCTAETHYLPORPHYRINOGEN; STEREOCHEMISTRY; SUSCEPTIBILITY; DERIVATIVES; CHEMISTRY;
D O I：
10.1002/anie.201106091
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
It's hip to be square: Two high-spin, square-planar {MO 4} complexes are prepared, including the first molecular example with M=Co II (see structure). Structural, spectroscopic, and magnetic susceptibility characterization allows a description of the ligand features required for this highly unusual electronic structure. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1000 / 1005
页数：6
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