High-Spin Square-Planar CoII and FeII Complexes and Reasons for Their Electronic Structure

被引：69

作者：

Cantalupo, Stefanie A. ^{[1
]}

Fiedler, Stephanie R. ^{[2
]}

Shores, Matthew P. ^{[2
]}

Rheingold, Arnold L. ^{[3
]}

Doerrer, Linda H. ^{[1
]}

机构：

[1] Boston Univ, Dept Chem, Boston, MA 02215 USA

[2] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

[3] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 04期

基金：

美国国家科学基金会;

关键词：

cobalt; electronic structure; high-spin complexes; iron; square-planar complexes; TRANSITION-METAL-COMPLEXES; CR QUADRUPLE BOND; CRYSTAL-STRUCTURES; COBALT(II) COMPLEXES; MAGNETIC-PROPERTIES; MESO-OCTAETHYLPORPHYRINOGEN; STEREOCHEMISTRY; SUSCEPTIBILITY; DERIVATIVES; CHEMISTRY;

D O I：

10.1002/anie.201106091

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It's hip to be square: Two high-spin, square-planar {MO 4} complexes are prepared, including the first molecular example with M=Co II (see structure). Structural, spectroscopic, and magnetic susceptibility characterization allows a description of the ligand features required for this highly unusual electronic structure. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1000 / 1005

页数：6

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