Perylene-Based All-Organic Redox Battery with Excellent Cycling Stability

被引：81

作者：

Iordache, Adriana ^{[1
,2
]}

Delhorbe, Virginie ^{[1
,2
]}

Bardet, Michel ^{[1
,3
]}

Dubois, Lionel ^{[1
,4
]}

Gutel, Thibaut ^{[1
,2
]}

Picard, Lionel ^{[1
,2
]}

机构：

[1] Univ Grenoble Alpes, F-38000 Grenoble, France

[2] Commissariat Energie Atom & Energies Alternat, Direct Rech Technol, Lab Innovat Technol Energies Nouvelles & Nanomat, Dept Elect Hydrogene Tranports,Serv Composants Ge, 17 Rue Martyrs, F-38054 Grenoble, France

[3] UMR E CEA UJF, Modelisat & Explorat Mat, Inst Nanosci & Cryogenie, Commissariat Energie Atom & Energies Alternat,Dir, 17 Rue Martyrs, F-38054 Grenoble, France

[4] UMR E CEA UJF, Syst Mol & Nanomat Energie & Sante, Inst Nanosci & Cryogenie, Commissariat Energie Atom & Energies Alternat,Dir, 17 Rue Martyrs, F-38054 Grenoble, France

来源：

ACS APPLIED MATERIALS & INTERFACES | 2016年 / 8卷 / 35期

关键词：

organic active material; perylene; greener compound; lithium-ion; all-organic battery; ELECTRODE MATERIALS; ANODE MATERIAL; PERFORMANCE; LI; POLYMERS; INSERTION;

D O I：

10.1021/acsami.6b07591

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Organic materials derived from biomass can constitute a viable option as replacements for inorganic materials in lithium-ion battery electrodes owing to their low production costs, recyclability, and structural diversity. Among them, conjugated carbonyls have become the most promising type of organic electrode material as they present high theoretical capacity, fast reaction kinetics, and quasi-infinite structural diversity. In this letter, we report a new perylene-based all-organic redox battery comprising two aromatic conjugated carbonyl electrode materials, the prelithiated tetra-lithium perylene-3,4,9,10-tetracarboxylate (PTCLi6) as negative electrode material and the poly(N-n-hexy1-3,4,9,10-perylene tetracarboxylic)imide (PTCI) as positive electrode material. The resulting battery shows promising long-term cycling stability up to 200 cycles. In view of the enhanced cycling performances, the two organic materials studied herein are proposed as suitable candidates for the development of new all-organic lithium-ion batteries.

引用

页码：22762 / 22767

页数：6

共 30 条

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