Vapor deposition polymerization of aniline on 3D hierarchical porous carbon with enhanced cycling stability as supercapacitor electrode

被引：110

作者：

Zhao, Yufeng ^{[1
,3
]}

Zhang, Zhi ^{[1
]}

Ren, Yuqin ^{[2
]}

Ran, Wei ^{[1
]}

Chen, Xinqi ^{[3
]}

Wu, Jinsong ^{[3
]}

Gao, Faming ^{[1
]}

机构：

[1] Yanshan Univ, Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China

[2] Chinese Acad Fishery Sci, Beidaihe Ctr Expt Stn, Beidaihe 066100, Peoples R China

[3] Northwestern Univ, NUANCE Ctr, EPIC, Evanston, IL 60208 USA

来源：

JOURNAL OF POWER SOURCES | 2015年 / 286卷

关键词：

Hierarchical porous; Composite; Supercapacitor; Electrochemical performance; POLYANILINE NANOWIRE ARRAYS; GRAPHENE OXIDE SHEETS; ASYMMETRIC SUPERCAPACITORS; ACTIVATED CARBONS; PERFORMANCE; COMPOSITE; FILM; FABRICATION; NANOSTRUCTURES; CAPACITANCE;

D O I：

10.1016/j.jpowsour.2015.03.141

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this work, a polyaniline coated hierarchical porous carbon (HPC) composite (PANI@HPC) is developed using a vapor deposition polymerization technique. The as synthesized composite is applied as the supercapacitor electrode material, and presents a high specific capacitance of 531 F g(-1) at current density of 0.5 A g(-1) and superior cycling stability of 96.1% (after 10,000 charge discharge cycles at current density of 10 A g(-1)). This can be attributed to the maximized synergistic effect of PANI and HPC. Furthermore, an aqueous symmetric supercapacitor device based on PANI@HPC is fabricated, demonstrating a high specific energy of 17.3 Wh kg(-1). (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：1 / 9

页数：9

共 62 条

[1] Synthesis of conductive polyaniline-graphite nanocomposite in supercritical CO2 and its application in zinc-rich epoxy primer [J].

Akbarinezhad, E. .

JOURNAL OF SUPERCRITICAL FLUIDS, 2014, 94 :8-16

[2] Progress in preparation, processing and applications of polyaniline [J].

Bhadra, Sambhu ;

Khastgir, Dipak ;

Singha, Nikhil K. ;

Lee, Joong Hee .

PROGRESS IN POLYMER SCIENCE, 2009, 34 (08) :783-810

[3] Polyaniline modified graphene and carbon nanotube composite electrode for asymmetric supercapacitors of high energy density [J].

Cheng, Qian ;

Tang, Jie ;

Shinya, Norio ;

Qin, Lu-Chang .

JOURNAL OF POWER SOURCES, 2013, 241 :423-428

[4] Polyaniline-Coated Electro-Etched Carbon Fiber Cloth Electrodes for Supercapacitors [J].

Cheng, Qian ;

Tang, Jie ;

Ma, Jun ;

Zhang, Han ;

Shinya, Norio ;

Qin, Lu-Chang .

JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (47) :23584-23590

[5]

CONWAY RE, 1999, ELECTROCHEMICAL SUPE

[6] Activated carbons from KOH-activation of argan (Argania spinosa) seed shells as supercapacitor electrodes [J].

Elmouwahidi, Abdelhakim ;

Zapata-Benabithe, Zulamita ;

Carrasco-Marin, Francisco ;

Moreno-Castilla, Carlos .

BIORESOURCE TECHNOLOGY, 2012, 111 :185-190

[7] Graphene-Wrapped Polyaniline Hollow Spheres As Novel Hybrid Electrode Materials for Supercapacitor Applications [J].

Fan, Wei ;

Zhang, Chao ;

Tjiu, Weng Weei ;

Pramoda, Kumari Pallathadka ;

He, Chaobin ;

Liu, Tianxi .

ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (08) :3382-3391

[8] Investigation of the capacitive performance of polyaniline/modified graphite composite electrodes [J].

Fan, Xinzhuang ;

Gao, Hai ;

Zhong, Lian ;

Xu, Haibo ;

Liu, Jianguo ;

Yan, Chuanwei .

RSC ADVANCES, 2015, 5 (05) :3743-3747

[9] Polyaniline nanostructures expedient as working electrode materials in supercapacitors [J].

Gedela, Venkata Ramana ;

Srikanth, Vadali Venkata Satya Siva .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2014, 115 (01) :189-197

[10] Preparation and characterization of high surface area, high porosity carbon monoliths from pyrolyzed bovine bone and their performance as supercapacitor electrodes [J].

Goodman, Paul A. ;

Li, H. ;

Gao, Y. ;

Lu, Y. F. ;

Stenger-Smith, J. D. ;

Redepenning, Jody .

CARBON, 2013, 55 :291-298

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