Molecular and polymeric hybrids based on covalently linked polyoxometalates and transition-metal complexes

被引：126

作者：

Kang, J

Xu, BB

Peng, ZH ^{[1
]}

Zhu, XD

Wei, YG

Powell, DR

机构：

[1] Univ Missouri, Dept Chem, Kansas City, MO 64110 USA

[2] Tsinghua Univ, Dept Chem, Beijing 100080, Peoples R China

[3] Univ Kansas, Dept Chem, Lawrence, KS 66045 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 42期

关键词：

C-C coupling; iron; molybdenum; organic-inorganic hybrids; polyoxometalates;

D O I：

10.1002/anie.200501924

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A rational building-block approach was employed to construct organometallic/ polyoxometalate (POM) hybrids in which POM clusters and transition-metal complexes are linked by a π-conjugated bridge. The synthetic strategy for molecular and polymeric hybrids - POM functionalization with iodo-bearing groups, attachment of a terpyridine-type ligand, and metal coordination - is shown schematically in the picture. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：6902 / 6905

页数：4

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