Removal of Basic Fuchsin dye from water using mussel shell biomass waste as an adsorbent: Equilibrium, kinetics, and thermodynamics

被引:95
作者
El Haddad, Mohammadine [1 ]
机构
[1] Univ Cadi Ayyad, Fac Poly Disciplinaire, Dept Chim, Equipe Chim Analyt & Environm, BP 4162, Safi 46000, Morocco
关键词
Dye removal; Adsorption; Calcined mussel shells; Basic dye; AQUEOUS-SOLUTIONS; ACTIVATED CARBON; METHYLENE-BLUE; ADSORPTION; BIOSORPTION; SAFRANIN;
D O I
10.1016/j.jtusci.2015.08.007
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The current study focused on the equilibrium, kinetics, and thermodynamics of Basic Fuchsin dye adsorption from aqueous solution using mussel shells as an adsorbent. Optimum adsorption conditions were identified by varying the solution pH, adsorbent dose, initial dye concentration, and contact time. Equilibrium data were fitted by the Langmuir, Freundlich and Dubinin-Radushkevich isotherm models, and a pseudo-second-order model best described the kinetics. Thermodynamic data showed that Basic Fuchsin dye adsorption onto mussel shells was a feasible, spontaneous and endothermic process. Statistical analysis was performed using the Chi-square (chi(2)) and mean square error (MSE) test methods to evaluate the best fit of the model to the experimental data. The adsorption of Basic Fuchsin by calcined mussel shells indicates their potential application as an adsorbent for the removal of dyes from aqueous solutions. (C) 2015 The Author. Production and hosting by Elsevier B.V. on behalf of Taibah University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.orgilicenses/by-nc-nd//4.0/).
引用
收藏
页码:664 / 674
页数:11
相关论文
共 22 条
[1]   EFFECTS OF COLORANTS IN THE AQUATIC ENVIRONMENT [J].
BROWN, D .
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 1987, 13 (02) :139-147
[2]   Comparison of Spirulina platensis microalgae and commercial activated carbon as adsorbents for the removal of Reactive Red 120 dye from aqueous effluents [J].
Cardoso, Natali F. ;
Lima, Eder C. ;
Royer, Betina ;
Bach, Marta V. ;
Dotto, Guilherme L. ;
Pinto, Luiz A. A. ;
Calvete, Tatiana .
JOURNAL OF HAZARDOUS MATERIALS, 2012, 241 :146-153
[3]   Adsorption of trihalomethanes by humin: Batch and fixed bed column studies [J].
Cunha, G. da C. ;
Romao, L. P. C. ;
Santos, M. C. ;
Araujo, B. R. ;
Navickiene, S. ;
de Padua, V. L. .
BIORESOURCE TECHNOLOGY, 2010, 101 (10) :3345-3354
[4]  
Dubinin MM., 1947, USSR PHYS CHEM SECT, V55, P331
[5]   Adsorptive removal of triarylmethane dye (Basic Red 9) from aqueous solution by sepiolite as effective and low-cost adsorbent [J].
Duman, Osman ;
Tunc, Sibel ;
Polat, Tulin Gurkan .
MICROPOROUS AND MESOPOROUS MATERIALS, 2015, 210 :176-184
[6]  
El Haddad M., 2012, J. Assoc. Arab. Univ. Basic. Appl. Sci, V12, P48, DOI DOI 10.1016/J.JAUBAS.2012.04.003
[7]   Evaluation of potential capability of calcined bones on the biosorption removal efficiency of safranin as cationic dye from aqueous solutions [J].
El Haddad, Mohammadine ;
Slimani, Rachid ;
Mamouni, Rachid ;
Rachid Laamari, My ;
Rafqah, Salah ;
Lazar, Said .
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2013, 44 (01) :13-18
[8]   Acidic dye wastewater treatment onto a marine macroalga, Nizamuddina zanardini (Phylum: Ochrophyta) [J].
Esmaeli, Alireza ;
Jokar, Mojtaba ;
Kousha, Masoud ;
Daneshvar, Ehsan ;
Zilouei, Hamid ;
Karimi, Keikhosro .
CHEMICAL ENGINEERING JOURNAL, 2013, 217 :329-336
[9]  
Freundlich H, 1906, Z PHYS CHEM-STOCH VE, V57, P385
[10]   Saccharomyces cerevisiae for the biosorption of basic dyes from binary component systems and the high order derivative spectrophotometric method for simultaneous analysis of Brilliant green and Methylene blue [J].
Ghaedi, Mehrorang ;
Hajati, Shaaker ;
Barazesh, Behnaz ;
Karimi, Farahnaz ;
Ghezelbash, Gholamreza .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2013, 19 (01) :227-233