Fast redox switching into the conducting state, related to single mono-cationic/polaronic charge carriers only in cation exchanger type conducting polymers

被引：11

作者：

Toth, Peter S. ^{[1
]}

Peintler-Krivan, Emese ^{[1
]}

Visy, Csaba ^{[1
]}

机构：

[1] Univ Szeged, Dept Phys Chem & Mat Sci, Szeged, Hungary

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2012年 / 18卷

关键词：

Conducting polymers; UV-vis-NER; a; c; conductance; EQCN; Redox mechanism; POLYPYRROLE; IMPEDANCE; POLYTHIOPHENES; BEHAVIOR; FILMS;

D O I：

10.1016/j.elecom.2012.02.005

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Simultaneously performed in situ conductance and spectro-electrochemical measurements completed by EQCN proved that fast redox switching can only be expected in cation exchanger type polymers, where the conductance develops promptly with the formation of mono-cationic/polaronic charge carriers due assumingly to the presence of the charge compensating anions in favorable distribution. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：16 / 19

页数：4