Synthesis of 5-Alkyl[3,4-c]thienopyrrole-4,6-dione-Based Polymers by Direct Heteroarylation

被引：216
作者：
Berrouard, Philippe [1 ]
Najari, Ahmed [1 ]
Pron, Agnieszka [1 ]
Gendron, David [1 ]
Morin, Pierre-Olivier [1 ]
Pouliot, Jean-Remi [1 ]
Veilleux, Justine [1 ]
Leclerc, Mario [1 ]
机构：
[1] Univ Laval, Dept Chem, Quebec City, PQ G1V 0A6, Canada
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 09期
基金：
加拿大自然科学与工程研究理事会;
关键词：
heteroarylation; homogeneous catalysis; palladium; polymerization; thieno[3; 4-c]pyrrole-4; 6-dione; CATALYZED DIRECT ARYLATION; HETEROJUNCTION SOLAR-CELLS; HETEROAROMATIC-COMPOUNDS; CRYSTALLINITY; DONOR;
D O I：
10.1002/anie.201106411
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Don't stand Stille: A direct heteroarylation polycondensation reaction was used for the synthesis of high-molecular-weight thienopyrroledione-based polymers (see scheme) in an impressive yield (up to 96 %) and in only a few synthetic steps. This new method is an alternative to the standard Stille coupling reaction and thus avoids formation of toxic tin by-products. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：2068 / 2071
页数：4
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