Condensate blockage alleviation around gas-condensate producing wells using wettability alteration

In the current survey, a novel fluorocarbon-based wettability modifier chemical is proposed to alter the wettability of sandstone rock surface from liquid wetting to preferentially gas wetting condition. Several experimental tests describing wettability condition of the rock surface including static contact angle measurements, spontaneous imbibition and dynamic core flooding using water and n-decane fluids were conducted on untreated and treated sandstone rock to investigate the effect of the proposed chemical on surface wetting behavior. Adsorption of fluorinated chemical on sandstone surfaces was characterized using FTIR and SEM. Elemental analysis of rock surface after treatment was determined by EDX analysis and EDX map. After chemical treatment of sandstone thin section, contact angles of water and n-decane in air-liquid-rock system were altered from 0 degrees and 0 degrees to 151 degrees and 101 degrees respectively. Spontaneous imbibition of water and n-decane as imbibing liquid fluids into the core sample saturated with dry air at room temperature on untreated and treated core showed that the ultimate amounts of liquid imbibitions were decreased to factors of 0.03 and 0.16 PV, demonstrating wettability alteration from strongly condensate-and water-wet to preferentially gas-wet condition, respectively. Also, the results of core flooding experiments demonstrated the improvement of liquid phase mobility as a result of treatment with proposed chemical fluid by factors of 3.85 and 3.5 for water and n-decane, respectively. The outcome of this integrated study proposes that fluorochemical agents can be considered as a promising candidate for possible field applications to alleviate both condensate and water blockage in gas condensate reservoirs by wettability alteration technique.