Synthesis, structure, and electrochemical properties of N,N′-bis(ferrocenylmethylene) ethylenediamine Schiff base and its metal complexes

被引：6

作者：

Kardas, Tugba Akcan ^{[1
]}

Ozbek, Hulya Avci ^{[1
]}

Akgul, Yurdanur ^{[2
]}

Demirhan, Funda ^{[1
]}

机构：

[1] Celal Bayar Univ, Fac Sci & Liberal Arts, Dept Chem, TR-45140 Manisa, Turkey

[2] Ege Univ, Fac Sci, Dept Chem, Bornova, Turkey

来源：

INORGANIC AND NANO-METAL CHEMISTRY | 2017年 / 47卷 / 10期

关键词：

Ferrocene; diimine ligands; Schiff base complexes; electrochemistry; cyclic voltammetry; NONLINEAR-OPTICAL PROPERTIES; LIGANDS;

D O I：

10.1080/24701556.2017.1357586

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of N,N '-bis(ferrocenylmethylene)ethylenediamine (FcNN) Schiff base with metal salts gave SnCl(4)FcNN (1), SnCl(2)FcNN(H2O)(2) (2), Sn-2(CH3)(4)Cl(4)FcNN (3), Ti(2)Cl(8)FcNN (4), CdFcNN(NO3)(2) (5), and CuFcNN(NO3)(2) (6). New complexes (1)-(6) were characterized by IR and elemental analysis techniques. IR spectra showed that the Schiff base was coordinated to the metal ions in a bidentate manner with N,N' donor sites. The H-1 NMR spectra of complexes (1), (2), and (4) show all the expected signals with a typical signal pattern of disubstituted ferrocenyl groups. The electrochemical properties of complexes were determined by cyclic voltammetry. Cyclic voltammetry results show that these complexes exhibit one irreversible oxidation peak.

引用

页码：1475 / 1479

页数：5

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