X-ray studies of polymer/gold nanocomposites

被引:46
作者
Lin, BH
Morkved, TL
Meron, M
Huang, ZQ
Viccaro, PJ
Jaeger, HM
Williams, SM
Schlossman, ML
机构
[1] James Franck Institute, Ctr. for Advanced Radiation Sources, University of Chicago, Chicago
[2] James Franck Institute, Department of Physics, University of Chicago, Chicago
[3] Department of Physics, University of Illinois (M/C 273), Chicago
[4] Department of Chemistry, University of Minnesota, Minneapolis
关键词
D O I
10.1063/1.369658
中图分类号
O59 [应用物理学];
学科分类号
摘要
We demonstrate that x-ray reflection standing wave fluorescence spectroscopy is a highly sensitive technique for the determination of the distribution of metal nanoparticles inside polymer thin films. We investigate both the depth profile and the in-plane spatial correlation of gold nanoparticles in an asymmetric polystyrene-b-poly(2-vinylpyridine) block copolymer film. These copolymer films self-assemble into alternating, nanometer-sized domains that are, upon annealing, selectively decorated by thermally evaporated metal nanoparticles to form metal/polymer composites. (C) 1999 American Institute of Physics. [S0021-8979(99)02706-1].
引用
收藏
页码:3180 / 3184
页数:5
相关论文
共 16 条
[1]   DIFFUSE-DOUBLE LAYER AT A MEMBRANE-AQUEOUS INTERFACE MEASURED WITH X-RAY STANDING WAVES [J].
BEDZYK, MJ ;
BOMMARITO, GM ;
CAFFREY, M ;
PENNER, TL .
SCIENCE, 1990, 248 (4951) :52-56
[2]   X-RAY STANDING WAVES AT A REFLECTING MIRROR SURFACE [J].
BEDZYK, MJ ;
BOMMARITO, GM ;
SCHILDKRAUT, JS .
PHYSICAL REVIEW LETTERS, 1989, 62 (12) :1376-1379
[3]   X-RAY STANDING WAVES - A MOLECULAR YARDSTICK FOR BIOLOGICAL-MEMBRANES [J].
BEDZYK, MJ ;
BILDERBACK, DH ;
BOMMARITO, GM ;
CAFFREY, M ;
SCHILDKRAUT, JS .
SCIENCE, 1988, 241 (4874) :1788-1791
[4]  
BOMMARITO GM, 1992, THESIS CORNELL U
[5]   Metal-polymer interactions in a polymer/metal nanocomposite [J].
Cole, DH ;
Shull, KR ;
Rehn, LE ;
Baldo, P .
PHYSICAL REVIEW LETTERS, 1997, 78 (26) :5006-5009
[6]   Fabrication of quantum dot/polymer composites: Phosphine-functionalized block copolymers as passivating hosts for cadmium selenide nanoclusters [J].
Fogg, DE ;
Radzilowski, LH ;
Blanski, R ;
Schrock, RR ;
Thomas, EL .
MACROMOLECULES, 1997, 30 (03) :417-426
[7]   Self-assembly and polymerization of epoxy resin amphiphilic block copolymer nanocomposites [J].
Hillmyer, MA ;
Lipic, PM ;
Hajduk, DA ;
Almdal, K ;
Bates, FS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (11) :2749-2750
[8]   Nanoscale patterning of barium titanate on block copolymers [J].
Lee, T ;
Yao, N ;
Aksay, IA .
LANGMUIR, 1997, 13 (14) :3866-3870
[9]  
Moller M, 1997, CURR OPIN COLLOID IN, V2, P177
[10]   MESOSCOPIC SELF-ASSEMBLY OF GOLD ISLANDS AN DIBLOCK-COPOLYMER FILMS [J].
MORKVED, TL ;
WILTZIUS, P ;
JAEGER, HM ;
GRIER, DG ;
WITTEN, TA .
APPLIED PHYSICS LETTERS, 1994, 64 (04) :422-424