Fabrication of Ti3C2Tx/In2O3 nanocomposites for enhanced ammonia sensing at room temperature

被引：34
作者：
Zhou, Ming [1 ]
Han, Yutong [2 ]
Yao, Yu [1 ]
Xie, Lili [1 ,3 ]
Zhao, Xueling [1 ,3 ]
Wang, Jingrong [1 ,3 ]
Zhu, Zhigang [1 ,2 ]
机构：
[1] Shanghai Polytech Univ, Coll Engn, Sch Environm & Mat Engn, Shanghai 201209, Peoples R China
[2] Univ Shanghai Sci & Technol, Sch Med Instrument & Food Engn, Shanghai 200093, Peoples R China
[3] Shanghai Polytech Univ, Shanghai Engn Res Ctr Adv Thermal Funct Mat, Shanghai 201209, Peoples R China
来源：
CERAMICS INTERNATIONAL | 2022年 / 48卷 / 05期
关键词：
NH3; Gas sensor; Ultrasonication; Nanocomposite; GAS SENSORS; ELECTROCHEMICAL PROPERTIES; ELECTRONIC-PROPERTIES; MXENE; COMPOSITE; NH3; PERFORMANCE; EMISSIONS; RECOVERY; V2C;
D O I：
10.1016/j.ceramint.2021.11.209
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Ti3C2Tx, as a novel two-dimensional material, displays promising prospects in NH3 detection at room temperature. However, the NH3 detection limit of pristine Ti3C2Tx is still a major research concern. Therefore, it is important to explore new Ti3C2Tx-based nanocomposites for better NH3-sensing performance. In the present experiment, Ti3C2Tx/In2O3 nanocomposites were successfully synthesized by ultrasonication and characterized by XRD, FESEM, TEM, XPS, and BET. The optimal Ti3C2Tx/In2O3-based sensor had a high response of 63.8% (30.4 times higher than that of pristine Ti3C2Tx) to 30 ppm NH3 at room temperature. In addition, the optimal Ti3C2Tx/In2O3-based sensor had stable repeatability, excellent selectivity, and long-term stability, while exhibiting excellent potential for NH3 detection at room temperature.
引用
收藏
页码：6600 / 6607
页数：8
相关论文
共 48 条
[1]   Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (Ti3C2TX MXene) [J].
Alhabeb, Mohamed ;
Maleski, Kathleen ;
Anasori, Babak ;
Lelyukh, Pavel ;
Clark, Leah ;
Sin, Saleesha ;
Gogotsi, Yury .
CHEMISTRY OF MATERIALS, 2017, 29 (18) :7633-7644
[2]   Control of electronic properties of 2D carbides (MXenes) by manipulating their transition metal layers [J].
Anasori, Babak ;
Shi, Chenyang ;
Moon, Eun Ju ;
Xie, Yu ;
Voigt, Cooper A. ;
Kent, Paul R. C. ;
May, Steven J. ;
Billinge, Simon J. L. ;
Barsoum, Michel W. ;
Gogotsi, Yury .
NANOSCALE HORIZONS, 2016, 1 (03) :227-234
[3]   2D/2D Heterojunction of Ultrathin MXene/Bi2WO6 Nanosheets for Improved Photocatalytic CO2 Reduction [J].
Cao, Shaowen ;
Shen, Baojia ;
Tong, Tong ;
Fu, Junwei ;
Yu, Jiaguo .
ADVANCED FUNCTIONAL MATERIALS, 2018, 28 (21)
[4]   Recovery of ammonia nitrogen from industrial wastewater treatment as Struvite slow releasing fertilizer [J].
El Diwani, G. ;
El Rafie, Sh. ;
El Ibiari, N. N. ;
El-Aila, H. I. .
DESALINATION, 2007, 214 (1-3) :200-214
[5]   Enhanced ammonia sensing performance based on MXene-Ti3C2Tx multilayer nanoflakes functionalized by tungsten trioxide nanoparticles [J].
Guo, Xuezheng ;
Ding, Yanqiao ;
Kuang, Delin ;
Wu, Zhilin ;
Sun, Xia ;
Du, Bingsheng ;
Liang, Chengyao ;
Wu, Yingjie ;
Qu, Weijie ;
Xiong, Lian ;
He, Yong .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2021, 595 :6-14
[6]   Flexible fabric gas sensors based on PANI/WO3p-n heterojunction for high performance NH3detection at room temperature [J].
He, Meng ;
Xie, Lili ;
Luo, Guifang ;
Li, Zhanhong ;
Wright, James ;
Zhu, Zhigang .
SCIENCE CHINA-MATERIALS, 2020, 63 (10) :2028-2039
[7]   CuO Nanoparticles/Ti3C2Tx MXene Hybrid Nanocomposites for Detection of Toluene Gas [J].
Hermawan, Angga ;
Zhang, Biao ;
Taufik, Ardiansyah ;
Asakura, Yusuke ;
Hasegawa, Takuya ;
Zhu, Jianfeng ;
Shi, Pei ;
Yin, Shu .
ACS APPLIED NANO MATERIALS, 2020, 3 (05) :4755-4766
[8]   Quantitative analysis of vaporous ammonia by online derivatization with gas chromatography - mass spectrometry with applications to ammonium nitrate-based explosives [J].
Katilie, Christopher J. ;
Simon, Alison G. ;
DeGreeff, Lauryn E. .
TALANTA, 2019, 193 :87-92
[9]   Titanium Carbide MXene as NH3 Sensor: Realistic First-Principles Study [J].
Khakbaz, Pedram ;
Moshayedi, Milad ;
Hajian, Sajjad ;
Soleimani, Maryam ;
Narakathu, Binu B. ;
Bazuin, Bradley J. ;
Pourfath, Mahdi ;
Atashbar, Massood Z. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2019, 123 (49) :29794-29803
[10]   Electronic properties and applications of MXenes: a theoretical review [J].
Khazaei, Mohammad ;
Ranjbar, Ahmad ;
Arai, Masao ;
Sasaki, Taizo ;
Yunoki, Seiji .
JOURNAL OF MATERIALS CHEMISTRY C, 2017, 5 (10) :2488-2503
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