The absorption coefficient of a polar liquid with solvated electrons

被引：0

作者：

Misurkin, I. A. ^{[1
]}

Titov, S. V. ^{[1
]}

机构：

[1] Karpov Res Inst Phys Chem, Moscow 105064, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2011年 / 85卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

polar liquid; solvated electron; absorption coefficient; quantum movements;

D O I：

10.1134/S0036024411050232

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An equation for the absorption coefficient of a polar liquid with excess (solvated) electrons is derived. It is taken into account that (1) each excess electron can for a certain time reside on only one liquid molecule (during this time, the molecule is in the anion-resonance state), and (2) a polar liquid is electrostatically nonuniform because it has different local potentials, which can be calculated for each molecule. The probabilities of quantum movements of excess electrons in a liquid from one molecule to another caused by the absorption of photons are considered.

引用

页码：821 / 825

页数：5

共 8 条

[1]

Anselm A.I., 1978, INTRO THEORY SEMICON

[2]

Berestetskii V. B., 1982, COURSE THEORETICAL P, V4

[3] On the transformation of light into heat in solids. I [J].