X-ray excited luminescent properties of apatitic compounds Ba5(PO4)3X (X: OH-, Cl-, Br-);: structure and hydroxyl ion conductivity of barium hydroxylapatite

被引：15

作者：

Duan, CJ ^{[1
]}

Wu, XY ^{[1
]}

Liu, W ^{[1
]}

Chen, HH ^{[1
]}

Yang, XX ^{[1
]}

Zhao, JT ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2005年 / 396卷 / 1-2期

关键词：

apatite; luminescence; x-ray excitation; ionic conductivity;

D O I：

10.1016/j.jallcom.2004.11.064

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ba-5(PO4)(3)X (X: OH-, Cl-, Br-) have been synthesized by the solid-state reaction methods. The X-ray excited luminescent properties of these compounds were investigated, and chloride and bromide compounds showed broad emission band with the peak center at about 400 nm while no luminescence of Ba-5(PO4)(3)OH had been observed. The structure of Ba-5(PO4)(3)OH was redetermined by X-ray powder diffraction methods and the result of Rietveld refinement is P6(3)/m, a = 10.1327(3) angstrom and c = 7.7526(3) angstrom. The ionic conductivity measurement of Ba-5 (PO4)(3)OH showed its ionic conductivity reached the maximum of 2.0 x 10(-6) S/cm at 400 degrees C with an activation energy as low as 0.43 eV due to the activity of OH groups along the channels. (c) 2004 Elsevier B.V. All rights reserved.

引用

页码：86 / 91

页数：6

共 8 条

[1] Alberius-Henning P, 2000, Z KRIST-NEW CRYST ST, V215, P345
[2] UBER ERDALKALIPHOSPHATE -ARSENATE UND -VANADATE VOM TYPUS 4MEO . X2O5
BAUER, H
BALZ, W
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1965, 340 (5-6): : 225 - &
[3] BONDAREVA OS, 1986, KRISTALLOGRAFIYA+, V31, P233
[4] Davis T. S., 1971, Journal of Luminescence, V4, P48, DOI 10.1016/0022-2313(71)90008-1
[5] Correction of zero shift in powder diffraction patterns using the reflection-pair method
Dong, C
Wu, F
Chen, H
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 : 850 - 853
[6] STRUCTURE OF BARIUM CHLORAPATITE
HATA, M
MARUMO, F
IWAI, S
AOKI, H
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (OCT): : 2382 - 2384
[7] RIETVELD HM, 1969, J APPL CRYSTALLOGR, V65, P2
[8] [No title captured]

← 1 →