Stability of Haynes 242 as metallic interconnects of solid oxide fuel cells (SOFCs)

被引:24
作者
Liu, Y. [1 ]
Zhu, J. [2 ]
机构
[1] Univ Connecticut, Inst Mat Sci, Dept Chem Mat & Biomol Engn, Storrs, CT 06269 USA
[2] Tennessee Technol Univ, Dept Mech Engn, Cookeville, TN 38505 USA
关键词
SOFC; Interconnect; Oxidation; Haynes; 242; Stability; MN-CO ALLOYS; OXIDATION RESISTANCE; STAINLESS-STEELS; SPINEL COATINGS; PERFORMANCE; BEHAVIOR; CATHODE;
D O I
10.1016/j.ijhydene.2010.05.053
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Haynes 242 is a unique Ni based alloy for interconnect application of solid oxide fuel cells (SOFCs), due to its low CTE (coefficient of thermal expansion) value which matches other fuel cell components over its peer of other Ni based alloys, together with very excellent oxidation resistance, and electrical conductive nature of the thermally grown oxide scales. A Ni-Mo rich intermetallic phase was observed to precipitate in this alloy during the thermal exposure in the SOFC environments and cause stability issue. This paper examined the stability of Haynes 242 in terms of oxidation resistance, electrical property, and oxidation kinetics as interconnects of solid oxide fuel cells. Results indicated that the precipitation helped significantly towards formation of NiO to reduce the Cr evaporation, and influenced little on oxidation resistance and electrical property. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:7936 / 7944
页数:9
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