Influence of kneading ratio on the binding interaction of coke aggregates on manufacturing a carbon block

被引:12
作者
Kim, Jong Gu [1 ,2 ]
Kim, Ji Hong [1 ,4 ]
Bai, Byong Choi [5 ]
Choi, Yun Jeong [1 ]
Im, Ji Sun [1 ,6 ]
Bae, Tae-Sung [3 ]
Lee, Young-Soak [2 ]
机构
[1] KRICT, Carbon Ind Frontier Res Ctr, Daejeon 34114, South Korea
[2] Chungnam Natl Univ, Inst Carbon Fus Technol, Daejeon 34134, South Korea
[3] Korea Basic Sci Inst, Jeonju Ctr, Jeonju 54907, South Korea
[4] Korea Univ, Dept Chem & Biol Engn, Seoul 02841, South Korea
[5] Korea Inst Convergence Text, Iksan, Jeollabuk Do, South Korea
[6] UST, Daejeon 34113, South Korea
关键词
kneading process; coke aggregates; carbon artifacts; binder pitch; carbonization; THERMAL-CONDUCTIVITY; NATURAL GRAPHITE; PITCH; GRAPHITIZATION; ELECTRODES;
D O I
10.5714/CL.2018.28.024
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Coke aggregates and carbon artifacts were produced to investigate the interactions of coke and pitch during the kneading process. In addition, the kneading ratio of the coke and binder pitch for the coke aggregates was controlled to identify the formation of voids and pores during carbonization at 900 degrees C. Experiments and thermogravimetric analysis revealed that carbon yields were improved over the theoretical yield calculated by the weight loss of the coke and binder pitch; the improvement was due to the binding interactions between the coke particles and binder pitch by the kneading process. The true, apparent, and bulk densities fluctuated according to the kneading ratio. This study confirmed that an excessive or insufficient kneading ratio decreases the density with degradation of the packing characteristics. The porosity analysis indicated that formation of voids and pores by the binder pitch increased the porosity after carbonization. Image analysis confirmed that the kneading ratio affected the formation of the coke domains and the voids and pores, which revealed the relations among the carbon yields, density, and porosity.
引用
收藏
页码:24 / 30
页数:7
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