On the Regeneration of Co3Mo3N from Co6Mo6N with N2

被引：51

作者：

Gregory, D. H. ^{[1
]}

Hargreaves, J. S. J. ^{[1
]}

Hunter, S. M. ^{[1
]}

机构：

[1] Univ Glasgow, WestCHEM, Sch Chem, Glasgow G12 8QQ, Lanark, Scotland

来源：

CATALYSIS LETTERS | 2011年 / 141卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

Nitrogen; Ammonia; Nitrides; Regeneration; Cobalt molybdenum nitride; AMMONIA-SYNTHESIS; LATTICE NITROGEN; NITRIDES; CATALYSTS; PHASE;

D O I：

10.1007/s10562-010-0464-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nitrogen has been demonstrated to be effective for the regeneration of Co3Mo3N from Co6Mo6N, albeit at higher temperature and longer duration than, when employing H-2/N-2. In some instances, incomplete regeneration yielding a mixture of the two line phases is observed, which has been interpreted on the possible basis of a crystallite size distribution. Temperature programmed reduction of Co3Mo3N, prepared so as to eliminate the possible contribution of NHx groups, demonstrates the significant production of ammonia although in much lower quantities than NHx-containing Co3Mo3N samples.

引用

页码：22 / 26

页数：5

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