Co-Gd phosphonate complexes as magnetic refrigerants

被引：226

作者：

Zheng, Yan-Zhen ^{[1
]}

Evangelisti, Marco ^{[3
]}

Winpenny, Richard E. P. ^{[1
,2
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[2] Univ Manchester, Photon Sci Inst, Manchester M13 9PL, Lancs, England

[3] Univ Zaragoza, Inst Ciencia Mat Aragon, CSIC, Dept Fis Mat Condensada, E-50009 Zaragoza, Spain

来源：

CHEMICAL SCIENCE | 2011年 / 2卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

MOLECULAR CLUSTERS; LIGANDS; CAGE; SPIN; SQUARE; GRIDS;

D O I：

10.1039/c0sc00371a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three 3d-4f phosphonate complexes, [(Co8Gd8III)-Gd-II(mu(3)-OH)(4)(NO3)(4)((O3PBu)-Bu-t)(8)((O2CBu)-Bu-t)(16)], [(Co8Gd4III)-Gd-II((O3PBu)-Bu-t)(6)((O2CBu)-Bu-t)(16)] and [(Co4Gd6III)-Gd-II(O3PCH2Ph)(6)((O2CBu)-Bu-t)(14)(MeCN)(2)], have been synthesized and have structures that can be related to molecular grids. Magnetic studies show they have promise as low temperature magnetic refrigerants.

引用

页码：99 / 102

页数：4

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