Synthesis, Structure and Magnetic Property of One NiII Based Coordination Polymer

被引：0

作者：

Wen Bo ^{[1
,2
]}

Wang Xiao-Dan ^{[2
]}

Yu Ying-Hui ^{[1
,2
]}

Gao Jin-Sheng ^{[1
,2
]}

Hou Guang-Feng ^{[1
]}

机构：

[1] Heilongjiang Univ, Engn Res Ctr Pesticide, Harbin 150080, Peoples R China

[2] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 33卷 / 11期

基金：

中国国家自然科学基金;

关键词：

Ni-II complex; crystal structure; coordination polymer; magnetism; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESIS; CADMIUM(II) COMPLEX; MOFS; MODULATION; ADSORPTION; LIGANDS; SYSTEM;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One new coordination polymer, [Ni(m-bix)(m-BDC)] (1, m-bix = 1,3-bis(imidazol-1-ylmethyl)benzene, m-BDC = 1,3-benzenedicarboxylic acids), has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, TGA and X-ray single-crystal diffraction. The green block crystal of complex 1 (C22H18N4NiO4) belongs to monoclinic system, space group P2(1)/c with a = 10.0418(3), b = 23.8651(6), c = 8.7872(2) angstrom, beta = 112.333(3)degrees, V = 1947.88(9) angstrom(3), Z = 4, D-c = 1.572 g/cm(3), M-r = 461.11, F(000) = 952, R = 0.0335 and wR = 0.0683 for 2827 observed reflections (I > 2 sigma(I)). Complex 1 exhibits a novel 6-connected 3D sxd type topological framework. The magnetic characterization of complex 1 shows antiferromagnetic coupling exchange.

引用

页码：1603 / 1609

页数：7

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