Numerical simulation of the electrode geometry and position effects on semiconductor gas sensor response

被引:44
作者
Vilanova, X
Llobet, E
Brezmes, J
Calderer, J
Correig, X
机构
[1] Univ Rovira & Virgili, Dept Elect Engn, Escola Tecn Super Engn, E-43006 Tarragona, Spain
[2] Univ Politecn Catalunya, Dept Elect Engn, ES-08034 Barcelona, Spain
关键词
electrode geometry; semiconductor gas sensor; numerical simulation; diffusion-adsorption-reaction model;
D O I
10.1016/S0925-4005(98)00080-X
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this work we have studied the coupled effects of electrode geometry and active film thickness on the sensitivity of semiconductor gas sensors to reducing gases. This study discusses a model that takes into account gas diffusion, adsorption and chemical reaction, to obtain the charge carrier concentration profile in the sensor bulk. The result is used in a two-dimensional semiconductor device simulation package to obtain the electrical conductance of the sensor in the presence of a reducing gas. Results show that all the parameters studied have an important effect on sensor response, especially when a highly reactive gas is being measured. Both electrode placement and film thickness must be considered if sensor sensitivity and selectivity are to be increased. For instance, if these parameters are chosen well, a poorly reactive gas can be detected in the presence of a highly reactive gas. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:425 / 431
页数:7
相关论文
共 8 条
[1]   A NONLINEAR DIFFUSION-REACTION MODEL OF ELECTRICAL-CONDUCTION IN SEMICONDUCTOR GAS SENSORS [J].
GARDNER, JW .
SENSORS AND ACTUATORS B-CHEMICAL, 1990, 1 (1-6) :166-170
[2]  
GARDNER JW, 1995, SENSOR ACTUAT B-CHEM, V26, P261
[3]   EFFECT OF ELECTRODE GEOMETRY ON SENSOR RESPONSE [J].
JAIN, U ;
HARKER, AH ;
STONEHAM, AM ;
WILLIAMS, DE .
SENSORS AND ACTUATORS B-CHEMICAL, 1990, 2 (02) :111-114
[4]  
Moseley P.T, 1987, SOLID STATE GAS SENS
[5]   EFFECTS OF DIFFUSIVITY OF HYDROGEN AND OXYGEN THROUGH PORES OF THICK-FILM SNO2-BASED SENSORS ON THEIR SENSING PROPERTIES [J].
SHIMIZU, Y ;
NAKAMURA, Y ;
EGASHIRA, M .
SENSORS AND ACTUATORS B-CHEMICAL, 1993, 13 (1-3) :128-131
[6]  
Tsuda N., 1991, ELECT CONDUCTION OXI
[7]   Analysis of the conductance transient in thick-film tin oxide gas sensors [J].
Vilanova, X ;
Llobet, E ;
Alcubilla, R ;
Sueiras, JE ;
Correig, X .
SENSORS AND ACTUATORS B-CHEMICAL, 1996, 31 (03) :175-180
[8]   THEORY OF SELF-DIAGNOSTIC SENSOR ARRAY DEVICES USING GAS-SENSITIVE RESISTORS [J].
WILLIAMS, DE ;
PRATT, KFE .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1995, 91 (13) :1961-1966