Transition metal-free electrocatalytic halodeborylation of arylboronic acids with metal halides MX (X = I, Br) to synthesize aryl halides

被引：36

作者：

Fu, Zhengjiang ^{[1
,2
]}

Hao, Guangguo ^{[1
]}

Fu, Yaping ^{[1
]}

He, Dongdong ^{[1
]}

Tuo, Xun ^{[1
]}

Guo, Shengmei ^{[1
]}

Cai, Hu ^{[1
]}

机构：

[1] Nanchang Univ, Coll Chem, Nanchang 330031, Jiangxi, Peoples R China

[2] State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2020年 / 7卷 / 03期

基金：

中国国家自然科学基金;

关键词：

C-H FUNCTIONALIZATION; ONE-POT CONVERSION; ORGANIC POLLUTANTS; CARBOXYLIC-ACIDS; HALOGENATION; IODINATION; STRATEGY; PHOTODEGRADATION; TRANSFORMATIONS; PHOTOREDUCTION;

D O I：

10.1039/c9qo01139k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient and regioselective ipso-halogenation of diverse arylboronic acids with metal halide salts MX (X = I, Br) has been well established under electrochemical conditions. A gram-scale reaction has been performed to evaluate the applicability of the protocol. Cyclic voltammetry experiments indicated that the halide anion was oxidized prior to the arylboronic acid substrate under standard conditions.

引用

页码：590 / 595

页数：6

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