Boosting the Nucleophilicity of Phosphole Lone Pairs by Isomerization

被引：13

作者：

Ciric, Ana ^{[1
]}

Mathey, Francois ^{[1
]}

机构：

[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore

来源：

ORGANOMETALLICS | 2010年 / 29卷 / 21期

关键词：

ARYL CHLORIDES; COMPLEXES;

D O I：

10.1021/om100423r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The phosphole isomer 4c can be obtained by nickelocene reduction complexation from the corresponding sulfide. It displays a ligating ability comparable to that of tristert-butylphosphine, and its [LPdCl2](2) complex efficiently catalyzes the deboronation homocoupling of arylboronic acids.

引用

页码：4785 / 4786

页数：2