Di(p-tert-butylphenyl)-N,N-di-(iso-butyl)carbamoylmethylphosphine oxide and its organotin and uranyl adducts:: structural and spectroscopic characterization

被引：46

作者：

Kapoor, RN

Guillory, P

Schulte, L

Cervantes-Lee, F

Haiduc, L

Parkanyi, L

Pannell, KH ^{[1
]}

机构：

[1] Univ Texas, Dept Chem, El Paso, TX 79968 USA

[2] Los Alamos Natl Lab, Actinide Chem Proc Grp, Los Alamos, NM 87545 USA

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2005年 / 19卷 / 04期

关键词：

carbamoylphosphine oxide; CMPO; organotin chlorides; uranyl;

D O I：

10.1002/aoc.847

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The single-crystal structure of the hydrophobic actinide extractant di(p-tert-butylphenyl)-N,N-di-(isobutyl)carbamoylmethylphosphine oxide (CMPO, 1) has been determined, as has that of its 1: 1 chelate complex with uranyl nitrate (2), its 1: 1 monodentate complexes with Ph3SnCl (3) and Me2SnCl2 (4) bonding via the P=O group. A 1:1 bidentate complex with Ph2SnCl2 bonding via both P=O and C=O functionalities (5) was obtained which in solution exhibits a C=O -> Sn bond dissociation to exist as the monodentate isomer coordinating only through the P=O group. Copyright (c) 2005 John Wiley & Sons, Ltd.

引用

页码：510 / 517

页数：8

共 43 条

[1] C-13 NMR-STUDIES OF SOME ORGANOTIN(IV) COMPOUNDS
ALALLAF, TAK
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 306 (03) : 337 - 346
[2] The Cambridge Structural Database: a quarter of a million crystal structures and rising
Allen, FH
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1): : 380 - 388
[3] ANTIPIN MY, 1985, ZH STRUKT KHIM, V26, P146
[4] Apodaca P, 2001, MAIN GROUP MET CHEM, V24, P597
[5] COBALT(II) AND NICKEL(II) COMPLEXES OF CARBAMYLMETHYLENEPHOSPHONATES
CATSIKIS, BD
GOOD, ML
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1974, 36 (05): : 1039 - 1042
[6] FORMATION AND CRYSTAL AND MOLECULAR-STRUCTURES OF DIOXOURANIUM(VI) COMPLEXES CONTAINING BIDENTATE CARBAMOYLMETHYLPHOSPHINATE AND PHOSPHINE OXIDE LIGANDS
CAUDLE, LJ
DUESLER, EN
PAINE, RT
[J]. INORGANICA CHIMICA ACTA-F-BLOCK ELEMENTS ARTICLES AND LETTERS, 1985, 110 (02): : 91 - 100
[7] PREPARATION AND STRUCTURE OF A NEODYMIUM COMPLEX CONTAINING BIDENTATE (CARBAMOYLMETHYL)PHOSPHINE OXIDE LIGANDS
CAUDLE, LJ
DUESLER, EN
PAINE, RT
[J]. INORGANIC CHEMISTRY, 1985, 24 (25) : 4441 - 4444
[8] A unique self-assembled tricyclic stannasiloxane containing a planar Sn3SiO5 fused 6.4.4 tricyclic ring system
Cervantes-Lee, F
Sharma, HK
Haiduc, I
Pannell, KH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (01): : 1 - 2
[9] Cherfa S, 1999, Z KRIST-NEW CRYST ST, V214, P523
[10] SYNTHESIS OF BIFUNCTIONAL PHOSPHONATES AND PHOSPHINE OXIDES - STRUCTURAL STUDIES OF 1-N,N-DIETHYL-CARBAMOYL-2-(4-HYDROXYLBENZENE)-ETHYL PHOSPHONIC ACID AND DIPHENYL[1-(N,N-DIETHYL-CARBAMOYL)-2-(PHENYL)ETHYL]PHOSPHINE OXIDE URANYL-NITRATE
CONARY, GS
MELINE, RL
CAUDLE, LJ
DUESLER, EN
PAINE, RT
[J]. INORGANICA CHIMICA ACTA, 1991, 189 (01) : 59 - 66

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