Regular polygonal micelles induced from fluorosilicone diblock copolymers

被引:7
作者
Cheng, Hua [1 ]
Li, Jin-Jin [1 ]
Luo, Zheng-Hong [1 ]
机构
[1] Xiamen Univ, Dept Chem & Biochem Engn, Coll Chem & Chem Engn, Xiamen, Peoples R China
基金
中国国家自然科学基金;
关键词
micelles; morphology; PDMS-b-PHFBMA; polygonal micelles; segregation; self-assembly; TEM; MULTIPLE MORPHOLOGIES; SURFACE; NANOPARTICLES; POLYMERS; BLOCK; DENDRONS; VESICLES;
D O I
10.1002/pola.25871
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Charming polygonal micelles: The self-assembly bahavior of fluorosilicone copolymers with equal block length could bring about the generation of novel large compound rods micelles and microsize vesicles. Interestingly, those vesicles are susceptible to the variation of pressure and regular polygonal micelles can be ultimately obtained for the first time. The possible mechanism can be proposed for the micelles morphology transition (see picture). Copyright © 2011 Wiley Periodicals, Inc.
引用
收藏
页码:1249 / 1253
页数:5
相关论文
共 31 条
  • [1] Alexander B., 2002, MACROMOLECULES, V35, P4929
  • [2] New perfluoropolyether urethane methacrylates as surface modifiers: Effect of molecular weight and end group structure
    Bonglovanni, Roberta
    Di Meo, Antonella
    Pollicino, Antonino
    Priola, Aldo
    Tonelli, Claudio
    [J]. REACTIVE & FUNCTIONAL POLYMERS, 2008, 68 (01) : 189 - 200
  • [3] Control of amphiphilic block copolymer morphologies using solution conditions
    Choucair, A
    Eisenberg, A
    [J]. EUROPEAN PHYSICAL JOURNAL E, 2003, 10 (01) : 37 - 44
  • [4] Self-assembly of polymer colloids and their solvatochromic-responsive properties
    Duan, Lingli
    You, Bo
    Zhou, Shuxue
    Wu, Limin
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (03) : 687 - 692
  • [5] Synthesis of fluorinated copoly(carbosiloxane)s by Pt-catalyzed hydrosilylation copolymerization
    Grunlan, MA
    Mabry, JM
    Weber, WP
    [J]. POLYMER, 2003, 44 (04) : 981 - 987
  • [6] HALPERIN A, 1992, ADV POLYM SCI, V100, P31
  • [7] Synthesis of novel well-defined chain-end- and in-chain-functionalized polystyrenes with one, two, three, and four perfluorooctyl groups and their surface characterization
    Hirao, A
    Koide, G
    Sugiyama, K
    [J]. MACROMOLECULES, 2002, 35 (20) : 7642 - 7651
  • [8] Dendronized Supramolecular Polymers Self-Assembled from Dendritic Ionic Liquids
    Imam, Mohammad R.
    Peterca, Mihai
    Edlund, Ulrica
    Balagurusamy, Venkatachalapathy S. K.
    Percec, Virgil
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (16) : 4165 - 4193
  • [9] Multicompartment micelles from ABC miktoarm stars in water
    Li, ZB
    Kesselman, E
    Talmon, Y
    Hillmyer, MA
    Lodge, TP
    [J]. SCIENCE, 2004, 306 (5693) : 98 - 101
  • [10] Access to the superstrong segregation regime with nonionic ABC copolymers
    Lodge, TP
    Hillmyer, MA
    Zhou, ZL
    Talmon, Y
    [J]. MACROMOLECULES, 2004, 37 (18) : 6680 - 6682