Modelling electrode transients: The strongly implicit procedure

被引：9

作者：

Alden, JA ^{[1
]}

Compton, RG ^{[1
]}

Dryfe, RAW ^{[1
]}

机构：

[1] UNIV OXFORD,PHYS & THEORET CHEM LAB,OXFORD OX1 3QZ,ENGLAND

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1996年 / 26卷 / 08期

关键词：

D O I：

10.1007/BF00683749

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The 'strongly implicit procedure' is shown to be a general, easy-to-use, stable and computationally efficient method of solving the mass transport equations necessary to predict transient voltammetric responses of electrode processes to which diffusion, convection and homogeneous chemical reaction may all contribute. The method is illustrated with a diversity of problems relating to electrodes of both micro- and milli-dimensions. In all cases excellent agreement with experiment and/or existing analytical or numerical theory is noted. Comparisons are made with alternative computational methods.

引用

页码：865 / 872

页数：8

共 26 条

[1] NUMERICAL-SIMULATION OF CONVECTIVE DIFFUSION AT A RECTANGULAR CHANNEL FLOW ELECTRODE [J].

ANDERSON, JL ;

MOLDOVEANU, S .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 179 (1-2) :107-117

[2] THEORY OF CHRONOAMPEROMETRIC CURVES FOR A SHORT-TIME AT MICROBAND ELECTRODES [J].

AOKI, K ;

TOKUDA, K ;

MATSUDA, H .

DENKI KAGAKU, 1986, 54 (12) :1010-1017

[3] DERIVATION OF AN APPROXIMATE EQUATION FOR CHRONOAMPEROMETRIC CURVES AT MICROBAND ELECTRODES AND ITS EXPERIMENTAL-VERIFICATION [J].

AOKI, K ;

TOKUDA, K ;

MATSUDA, H .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 230 (1-2) :61-67

[4]

AOKI K, 1993, ELECTROANAL, V5, P1

[5]

Britz D., 1988, DIGITAL SIMULATION E

[6] PRIMITIVE VARIABLE, STRONGLY IMPLICIT CALCULATION PROCEDURE FOR VISCOUS FLOWS AT ALL SPEEDS [J].

CHEN, KH ;

PLETCHER, RH .

AIAA JOURNAL, 1991, 29 (08) :1241-1249

[7] HYDRODYNAMIC VOLTAMMETRY WITH CHANNEL MICROBAND ELECTRODES - POTENTIAL STEP TRANSIENTS [J].

COMPTON, RG ;

DRYFE, RAW ;

ALDEN, JA ;

REES, NV ;

DOBSON, PJ ;

LEIGH, PA .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (04) :1270-1275

[8] MODELING ELECTRODE-REACTIONS USING THE STRONGLY IMPLICIT PROCEDURE [J].

COMPTON, RG ;

DRYFE, RAW ;

WELLINGTON, RG ;

HIRST, J .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 383 (1-2) :13-19

[9] HYDRODYNAMIC VOLTAMMETRY WITH CHANNEL MICROBAND ELECTRODES - RESOLUTION OF ECE AND DISP1 PROCESSES [J].

COMPTON, RG ;

WELLINGTON, RG ;

DOBSON, PJ ;

LEIGH, PA .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 370 (1-2) :129-133

[10]

Cottrell FG, 1903, Z PHYS CHEM-STOCH VE, V42, P385

← 1 2 3 →