Metal-porphyrin in epoxidation of olefins: Recent advances

被引：12
作者：
Ahmad, Irshad [1 ]
Shagufta [1 ]
Rehman, Sadia [2 ]
机构：
[1] Amer Univ Ras Al Khaimah, Sch Arts & Sci, Dept Math & Nat Sci, Ras Al Khaymah, U Arab Emirates
[2] Amer Univ Ras Al Khaimah, Sch Engn, Dept Chem Engn, Ras Al Khaymah, U Arab Emirates
来源：
TETRAHEDRON | 2022年 / 104卷
关键词：
Asymmetric; Catalysis; Epoxidation; Heterogeneous; Homogeneous; Porphyrins; OXYGEN-ATOM TRANSFER; ASYMMETRIC EPOXIDATION; ENANTIOSELECTIVE EPOXIDATION; HYDROGEN-PEROXIDE; AEROBIC OXIDATION; HIGHLY EFFICIENT; MN-PORPHYRIN; UNFUNCTIONALIZED OLEFINS; CHIRAL METALLOPORPHYRINS; MANGANESE-PORPHYRINS;
D O I：
10.1016/j.tet.2021.132604
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The application of cytochrome P-450 inspired metal-porphyrin catalysts within the oxidation reaction, predominantly in olefin epoxidation, has advanced as a trending topic in research. A strenuous effort has been made to summarize the catalytic activity of the most promising metal-porphyrin-based homogeneous and heterogeneous catalysts reported in the literature for the various olefins and cyclic enones epoxidation. This mini-review provides a practical and comprehensive vision for understanding homogeneous and heterogeneous metalloporphyrin-based catalysis and covers the recent advancement of a modern, novel catalytic framework for oxidation chemistry. (C) 2021 Elsevier Ltd. All rights reserved.
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页数：22
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