Metal-porphyrin in epoxidation of olefins: Recent advances

被引：12

作者：

Ahmad, Irshad ^{[1
]}

Shagufta ^{[1
]}

Rehman, Sadia ^{[2
]}

机构：

[1] Amer Univ Ras Al Khaimah, Sch Arts & Sci, Dept Math & Nat Sci, Ras Al Khaymah, U Arab Emirates

[2] Amer Univ Ras Al Khaimah, Sch Engn, Dept Chem Engn, Ras Al Khaymah, U Arab Emirates

来源：

TETRAHEDRON | 2022年 / 104卷

关键词：

Asymmetric; Catalysis; Epoxidation; Heterogeneous; Homogeneous; Porphyrins; OXYGEN-ATOM TRANSFER; ASYMMETRIC EPOXIDATION; ENANTIOSELECTIVE EPOXIDATION; HYDROGEN-PEROXIDE; AEROBIC OXIDATION; HIGHLY EFFICIENT; MN-PORPHYRIN; UNFUNCTIONALIZED OLEFINS; CHIRAL METALLOPORPHYRINS; MANGANESE-PORPHYRINS;

D O I：

10.1016/j.tet.2021.132604

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The application of cytochrome P-450 inspired metal-porphyrin catalysts within the oxidation reaction, predominantly in olefin epoxidation, has advanced as a trending topic in research. A strenuous effort has been made to summarize the catalytic activity of the most promising metal-porphyrin-based homogeneous and heterogeneous catalysts reported in the literature for the various olefins and cyclic enones epoxidation. This mini-review provides a practical and comprehensive vision for understanding homogeneous and heterogeneous metalloporphyrin-based catalysis and covers the recent advancement of a modern, novel catalytic framework for oxidation chemistry. (C) 2021 Elsevier Ltd. All rights reserved.

引用

页数：22

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