A simple synthesis of nitrogen-sulfur co-doped porous carbon using ionic liquids as dopant for high rate performance Li-ion batteries

被引:13
作者
Du, Mengqi [1 ]
Meng, Yanshuang [1 ]
Wang, Chen [1 ]
Duan, Chaoyu [1 ]
Zhu, Fuliang [1 ,3 ]
Zhang, Yue [2 ]
机构
[1] Lanzhou Univ Technol, Sch Mat Sci & Engn, Lanzhou 730050, Gansu, Peoples R China
[2] Georgia Southern Univ, Dept Mfg Engn, Statesboro, GA 30458 USA
[3] State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Gansu, Peoples R China
基金
中国国家自然科学基金;
关键词
Nitrogen-sulfur co-doping porous carbon; Ionic liquids; Lithium ion batteries anode material; Salt template; TEMPLATE-FREE SYNTHESIS; HIGH-CAPACITY ANODE; ORIENTED GRAPHENE; LITHIUM STORAGE; OXIDE; NANOPARTICLES; MICROSPHERES; NANOSPHERES; NANOSHEETS; ELECTRODE;
D O I
10.1016/j.jelechem.2018.12.042
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A novel nitrogen-sulfur co-doped porous carbon (NSPC) material was synthesized by using ionic liquids as the nitrogen and sulfur precursor. This material exhibited porous structure with high specific surface area (701 m(2) g(-1)) and superior nitrogen and sulfur co-doping (4.66 and 1.83 wt%, respectively), The materials was used as anode materials for Lithium-ion batteries and showed a high reversible capacity of 987.7 mAh g(-1) at a current density of 0.1 A g(-1) and a good long cycle performance (337.5 mAh g(-1) at 5 A g(-1) after 5000 cycles). The NSPC's superior electrochemical performance can be attributed to three points: (1) Excellent pore structure (surface area is 701 m(2) g(-1)). (2) Nitrogen and sulfur co-doping (4.66 and 1.83 wt%, respectively). (3) Higher rate of capacitance contribution during process of charge and discharge.
引用
收藏
页码:17 / 25
页数:9
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