Synthesis and electrochemical properties of bis(octacyanophthalocyaninato)neodymium(III) complex

被引：7

作者：

Yonekura, T ^{[1
]}

Ohsaka, T ^{[1
]}

Kitamura, F ^{[1
]}

Tokuda, K ^{[1
]}

机构：

[1] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2005年 / 9卷 / 01期

关键词：

neodymium(III); octacyanophthalocyanine; synthesis; electrochemical property;

D O I：

10.1142/S1088424605000101

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bis(octacyanophthalocyaninato)neodymium(III) was synthesized and its electrochemical behavior in N,N-dimethylformamide (DMF) was investigated by cyclic voltammetry (CV) and square wave voltammetry (SWV). Multiple redox reactions were observed on the cyclic voltammogram, although the voltammetric feature was complicated due to aggregation. With the aid of SWV, it was concluded that the redox potentials of the complex positively shifted by about 700 mV compared with potentials of the unsubstituted complex, which was ascribed to the strong electron-withdrawn effect of the substituted cyano group. Copyright (c) 2005 Society of Porphyrins & Phthalocyanines.

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收藏

页码：54 / 58

页数：5

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