Co(II), Cu(II) and Zn(II) Complexes of N, O-Type Schiff Base Ligand Derived from 4,4′-Methylenedianiline Synthesis, Characterization, Antibacterial and Antifungal Studies

被引:0
作者
Sahal, Hakan [1 ,3 ]
Canpolat, Erdal [2 ]
Kaya, Mehmet [1 ,3 ]
Gur, Seher
机构
[1] Firat Univ, Dept Chem, Fac Sci, TR-23119 Elazig, Turkey
[2] Firat Univ, Dept Elementary Sci Educ, Fac Educ, TR-23119 Elazig, Turkey
[3] Firat Univ, Dept Biol, Fac Sci, TR-23119 Elazig, Turkey
来源
JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN | 2017年 / 39卷 / 04期
关键词
Schiff base; Antimicrobial activity; Antifungal activity; Transition metal complexes; METAL-COMPLEXES; VIC-DIOXIME; COPPER(II) COMPLEXES; NI(II); MONONUCLEAR; NICKEL(II); COBALT(II); ZINC(II); ACID;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three new complexes were prepared reacting Co(II), Cu(II) and Zn(II) salts with 2-[(E)-{[4-(4-aminobenzyl) phenyl]imino}methyl]-6-ethoxyphenol (LH) and characterized by analytical and spectrocemical methods. The metal: ligand stoichiometric ratio is 1:1 in the complexes of Co(II) and Zn(II), whereas in the Cu(II) complex, the metal: ligand stoichiometric ratio is 2:1. It was determined that bidentate behavior of the ligand is accomplished via the phenolic oxygen and the azomethine nitrogen atoms. The presence of water is revealed by thermograms and supported by the presence of relevant bonds in their IR spectra. These new complexes showed a reasonable amount antifungal activity.
引用
收藏
页码:544 / 551
页数:8
相关论文
共 36 条
[1]   Group VI dinuclear oxo metal complexes of salicylideneimine-2-anisole Schiff base [J].
Ali, OAM ;
Khalil, MMH ;
Attia, GM ;
Ramadan, RM .
SPECTROSCOPY LETTERS, 2003, 36 (1-2) :71-82
[2]   SOME COMMENTS ON THE ANOMALOUS MAGNETIC BEHAVIOR OF CERTAIN NI(II) COMPLEXES [J].
BALLHAUSEN, CJ ;
LIEHR, AD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (03) :538-542
[3]  
Bi CF, 2000, J RADIOANAL NUCL CH, V246, P221
[4]   Ancistrotanzanine C and related 5,1′- and 7,3′-coupled naphthylisoquinoline alkaloids from Ancistrocladus tanzaniensis [J].
Bringmann, G ;
Dreyer, M ;
Faber, JH ;
Dalsgaard, PW ;
Staerk, D ;
Jaroszewski, JW ;
Ndangalasi, H ;
Mbago, F ;
Brun, R ;
Christensen, SB .
JOURNAL OF NATURAL PRODUCTS, 2004, 67 (05) :743-748
[5]   Synthesis and characterization of a vic-dioxime derivative and investigation of its complexes with Ni(II), Co(II), Cu(II) and UO2(VI)metals [J].
Canpolat, E ;
Kaya, M .
JOURNAL OF COORDINATION CHEMISTRY, 2002, 55 (08) :961-968
[6]   Synthesis and formation of a new vic-dioxime complexes [J].
Canpolat, E ;
Kaya, M .
JOURNAL OF COORDINATION CHEMISTRY, 2005, 58 (14) :1217-1224
[7]  
Canpolat E, 2005, POL J CHEM, V79, P619
[8]   Mononuclear chelates derived from substituted Schiff base ligands:: Synthesis and characterization of a new 3-methoxysalicyliden-p-aminoacetophenoneoxime and its complexes with Co(II), Ni(II), Cu(II), and Zn(II) [J].
Canpolat, E ;
Kaya, M ;
Yazici, A .
SPECTROSCOPY LETTERS, 2005, 38 (01) :35-45
[9]   Synthesis and characterization of two vic-dioximes containing the 1,3-dioxolane ring and 1,4-diaminobutane and their cobalt(II), nickel(II), copper(II) and zinc(II) metal complexes [J].
Canpolat, E ;
Kaya, M .
TRANSITION METAL CHEMISTRY, 2004, 29 (05) :550-556
[10]  
Canpolat E, 2004, TURK J CHEM, V28, P235